Layer-by-layer zinc metal anodes to achieve long-life zinc-ion batteries

被引：71
作者：
Huang, Yongfeng [1 ,2 ]
Chang, Ziwen [1 ,2 ]
Liu, Wenbao [1 ,2 ]
Huang, Wenting [1 ,2 ]
Dong, Liubing [3 ]
Kang, Feiyu [1 ]
Xu, Chengjun [1 ]
机构：
[1] Tsinghua Univ, Shenzhen Geim Graphene Ctr, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China
[2] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[3] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 511443, Peoples R China
来源：
CHEMICAL ENGINEERING JOURNAL | 2022年 / 431卷
基金：
对外科技合作项目（国际科技项目）;
关键词：
Zinc-ion batteries; Zinc metal anodes; Layer-by-layer construction; Sn; Cu; Zn composite anode; TOTAL-ENERGY CALCULATIONS; ZN; ELECTRODEPOSITION; PERFORMANCE; CAPACITY; DENSITY; STORAGE; POWDER; LIQUID; COPPER;
D O I：
10.1016/j.cej.2021.133902
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Aqueous rechargeable zinc-ion batteries have attracted much attention due to high safety, fast charge/discharge rate, low cost and direct utilization of zinc metal anodes. However, zinc anodes suffer from fundamental issues and elusiveness of critical information such as its nucleation and plating/stripping behaviors. Herein, we explore nucleation pattern of zinc on various metal substrates (Cu, Ag, Ti or Sn) and discover a substrate-dependent plating/stripping behavior. With use of binary diagrams (Ag|Cu, Ti|Cu and Cu|Sn), we found that zinc has a selective deposition on Cu substrates with no nucleation barriers. Theoretical calculation also indicates a relatively low bonding energy between Zn and Cu. Besides, it is also found that Sn inhibits growth of by-product of basic zinc sulfates. Thereafter, we report a layer-by-layer construction of zinc metal (Sn/Cu/Zn) anode for long life zinc-ion batteries. Our work paves a way to understand plating/stripping behavior of metal anodes and to design layer-by-layer metal anodes for metal batteries.
引用
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页数：9
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