Function of triazenido compound for electrocatalytic hydrogen production catalyzed by platinum complex

被引：5

作者：

Zhang, Yun-Xiao ^{[1
]}

Lin, Chen-Neng ^{[1
]}

Zhan, Shu-Zhong ^{[1
]}

机构：

[1] South China Univ Technol, Coll Chem & Chem Engn, Guangzhou, Guangdong, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 69卷 / 19期

基金：

美国国家科学基金会;

关键词：

Triazenido compound; platinum complex; molecular catalyst; hydrogen generation; MOLECULAR ELECTRO-CATALYST; GENERATING HYDROGEN; ACETIC-ACID; CRYSTAL-STRUCTURES; WATER; EVOLUTION; ELECTROCHEMISTRY; PALLADIUM; CLUSTER; LIGAND;

D O I：

10.1080/00958972.2016.1219350

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new type of electrocatalyst based on a triazenido-platinum complex, Pt(PPh3)(2)(L)Cl (1), is prepared by the reaction of 1-[(2-methoxy) benzene]-3-[2-pyridine] triazene (HL) and Pt(PPh3)(2)Cl-2 in the presence of triethylamine. Electrochemical studies indicate that HL, Pt(PPh3)(2)Cl-2 and 1 can catalyze hydrogen evolution from acetic acid or a neutral buffer. To show triazenido ligand, HL, plays a role in determining the catalytic activities of the platinum complex, we systematically study the electrocatalytic activities of HL, Pt(PPh3)(2)Cl-2 and Pt(PPh3)(2)(L)Cl and provide a possible catalytic mechanism for hydrogen generation catalyzed by 1.

引用

页码：2832 / 2844

页数：13

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