Bifunctional Acid Catalysts for Organic Synthesis

被引：31
|
作者：
Li, Pingfan [1 ]
Yamamoto, Hisashi [1 ]
机构：
[1] Univ Chicago, Dept Chem, 5735 S Ellis Ave, Chicago, IL 60637 USA
来源：
BIFUNCTIONAL MOLECULAR CATALYSIS | 2011年 / 37卷
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
Asymmetric synthesis; Bifunctional acid catalysis; Combined acid catalysis; Cooperative acid catalysis; Designer acid; CHIRAL BRONSTED ACID; DIELS-ALDER REACTIONS; FRIEDEL-CRAFTS ALKYLATION; C-2-SYMMETRIC TRIDENTATE BIS(OXAZOLINE); ASYMMETRIC MICHAEL ADDITION; SILYL ENOL ETHERS; LEWIS-ACID; C-H; ENANTIOSELECTIVE PROTONATION; COOPERATIVE CATALYSIS;
D O I：
10.1007/3418_2011_4
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The concept of bifunctional acid catalysis is very helpful for inventing new catalytic asymmetric reactions. Compared with single functional acid catalysts, cooperative effect of two acid components has the potential to fine tune the reactivity as well as the selectivity of desired reaction pathways. This chapter focuses on some representative examples on the recent developments of bifunctional acid catalysis, including combined acid catalysis and other cooperative acid catalysis.
引用
收藏
页码：161 / +
页数：4
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