Comparing catalytic properties of copper loaded CeO2 and SnO2 oxides catalysts for CO oxidation

被引:0
作者
Smid, B.
Hanys, P. [1 ]
Frey, K.
Mori, T. [1 ]
Takahashi, M. [1 ]
Matolinova, I.
Matolin, V.
机构
[1] Natl Inst Mat Sci, Fuel Cell Mat Ctr, Nano Ion Mat Grp, Tsukuba, Ibaraki 3050044, Japan
来源
TRANSACTIONS OF THE MATERIALS RESEARCH SOCIETY OF JAPAN, VOL 32, NO 4 | 2007年 / 32卷 / 04期
关键词
nano-sized catalytic systems; copper; ceria; tin oxide; CO oxidation;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Catalytic properties of systems composed of copper loaded CeO2 and SnO2 were examined. Catalysts were prepared using a conventional impregnation method. After preparation the samples were calcined in oxygen respective reduced in hydrogen. Treatments were carried out at 400 degrees C resp. 300 degrees C for 2 hours. The amount of copper in prepared samples was 8 at. % in both cases. Morphology and particle size were observed using Scanning Electron Microscopy (SEM). Crystal phases were characterized by X-Ray Diffraction method (XRD). The CO oxidation reaction was performed in a flow micro-reactor in the mixture of He, O-2 and CO, where the catalyst was deposited on a silicon oxide chip ensuring a very reliable catalyst temperature control. It can be expected that nano-structured copper loaded oxide catalysts could be used for removing CO produced in a wet reforming reaction for fuel cell applications.
引用
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页码:1023 / 1026
页数:4
相关论文
共 18 条
  • [1] ANTON M, 1994, SENSOR ACTUAT B-CHEM, V18, P500
  • [2] Studies on Cu/CeO2:: A new NO reduction catalyst
    Bera, P
    Aruna, ST
    Patil, KC
    Hegde, MS
    [J]. JOURNAL OF CATALYSIS, 1999, 186 (01) : 36 - 44
  • [3] THE INTERACTION OF TIN OXIDE-FILMS WITH O2, H-2, NO, AND H2S
    CAPEHART, TW
    CHANG, SC
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1981, 18 (02): : 393 - 397
  • [4] Fast response H2S gas sensing characteristics with ultra-thin CuO islands on sputtered SnO2
    Chowdhuri, A
    Gupta, V
    Sreenivas, K
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) : 572 - 579
  • [5] COPPER-DOPING LEVEL EFFECT ON SENSITIVITY AND SELECTIVITY OF TIN OXIDE THIN-FILM GAS SENSOR
    GALDIKAS, A
    MIRONAS, A
    SETKUS, A
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1995, 26 (1-3) : 29 - 32
  • [6] JANSSEN FJ, 1997, HDB HETEROGENEOUS CA, V4, P1633
  • [7] The influence of Rh surface doping on anomalous properties of thick-film SnO2 gas sensors
    Licznerski, BW
    Nitsch, K
    Teterycz, H
    Wisniewski, K
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2001, 79 (2-3) : 157 - 162
  • [8] COMPLETE OXIDATION OF CARBON-MONOXIDE AND METHANE OVER METAL-PROMOTED FLUORITE OXIDE CATALYSTS
    LIU, W
    SAROFIM, AF
    FLYTZANI-STEPHANOPOULOS, M
    [J]. CHEMICAL ENGINEERING SCIENCE, 1994, 49 (24A) : 4871 - 4888
  • [9] TOTAL OXIDATION OF CARBON-MONOXIDE AND METHANE OVER TRANSITION METAL-FLUORITE OXIDE COMPOSITE CATALYSTS .1. CATALYST COMPOSITION AND ACTIVITY
    LIU, W
    FLYTZANI-STEPHANOPOULOS, M
    [J]. JOURNAL OF CATALYSIS, 1995, 153 (02) : 304 - 316
  • [10] Influence of particle morphology on nanostructural feature and conducting property in Sm-doped CeO2 sintered body
    Mori, T
    Wang, YR
    Drennan, J
    Auchterlonie, G
    Li, JG
    Ikegami, T
    [J]. SOLID STATE IONICS, 2004, 175 (1-4) : 641 - 649