1D lanthanide coordination polymers containing biphosphonate ligand: Synthesis, structures and luminescence properties

被引：8

作者：

Lu, Yan-Lei ^{[1
]}

Ma, Yan ^{[1
]}

Sun, Ling-Zhi ^{[1
]}

Kuang, Xiao-Nan ^{[1
]}

Xin, Xiu-Lan ^{[2
]}

Han, Hong-Liang ^{[1
]}

Liu, Min ^{[3
]}

Li, Zhong-Feng ^{[1
]}

Jin, Qiong-Hua ^{[1
]}

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China

[2] Beijing Technol & Business Univ, Sch Light Ind, Beijing 100048, Peoples R China

[3] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2020年 / 118卷

基金：

北京市自然科学基金; 中国国家自然科学基金;

关键词：

Lanthanide complexes; Bisphosphonate ligand; Crystal structure; Luminescence; TIME-DOMAIN SPECTROSCOPY; COMPLEXES; METAL; CONTRACTION; EXTRACTION; MAGNETS; MOFS; LN;

D O I：

10.1016/j.inoche.2020.108045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six novel lanthanide complexes [LnL(Phen)Cl-3] n (1-6) (Ln = Sm, Eu, Gd, Tb, Dy, Ho) (L = tetraethyl ethylenebisphosphonate, Phen = 1,10-phenanthroline) have been synthesized through a simple one-pot reaction. Complexes 1-6 are of 1D infinite chain structure. The CeH center dot center dot center dot pi interactions and the bridging action of L ligand lead to the formation of 3D network structures for 1-6. Emission spectra of complexes 1, 2, 4 and 5 show characteristic emission peaks of Sm3+, Eu3+, Tb3+ and Dy3+, respectively. Quantum yield of 2 is up to 37% while that of 4 reaches 31% in solid state, so they can be used as potential luminescent materials.

引用

页数：6

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