Two stable 3D porous metal-organic frameworks with high performance for gas adsorption and separation

被引：94

作者：

Yao, Shuo ^{[1
]}

Wang, Dongmei ^{[1
]}

Cao, Yu ^{[1
]}

Li, Guanghua ^{[1
]}

Huo, Qisheng ^{[1
]}

Liu, Yunling ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 32期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; CO2; ADSORPTION; SELECTIVE SEPARATION; SORPTION; EFFICIENT; BINDING; STABILITY; TOPOLOGY; POLYMER; SITES;

D O I：

10.1039/c5ta03886c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two porous MOFs, [NO3][In3OL3]center dot 4DMF center dot 3H(2)O (JLU-Liu18) and [CdL]center dot 0.5DMF (JLU-Liu19), H2L - pyridine-3,5- bis(phenyl-4-carboxylic acid), have been solvothermally synthesized and structurally characterized. Both of the two compounds possess a saturated coordination metal centre without open metal sites (OMSs) leading to remarkable thermal and water vapour stability. JLU-Liu18 displays a rare occurrence of 9-connected, trinuclear [In3O(CO2)(6)N-3] secondary building units (SBUs) in a porous crystal, with high adsorption for small gases, especially CO2 (129 and 400 cm(3) g(-1) at 273 and 195 K, respectively, under 1 bar). It also performs with commendable selectivity for O-2 over N-2, and CO2, C2H6, C3H8 over CH4. JLU-Liu19 possesses outstanding performance for sieving small gases owing to its ultramicropores of 3.5 angstrom. Both of the two MOFs are promising materials for gas adsorption and purification.

引用

页码：16627 / 16632

页数：6

共 54 条

[1]

[Anonymous], 1997, SHELXTL NT VERSION 5

[2] A stable metal-organic framework with suitable pore sizes and rich uncoordinated nitrogen atoms on the internal surface of micropores for highly efficient CO2 capture [J].

Bao, Shao-Juan ;

Krishna, Rajamani ;

He, Ya-Bing ;

Qin, Jun-Sheng ;

Su, Zhong-Min ;

Li, Shun-Li ;

Xie, Wei ;

Du, Dong-Ying ;

He, Wen-Wen ;

Zhang, Shu-Ran ;

Lan, Ya-Qian .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (14) :7361-7367

[3] Applied Topological Analysis of Crystal Structures with the Program Package ToposPro [J].

Blatov, Vladislav A. ;

Shevchenko, Alexander P. ;

Proserpio, Davide M. .

CRYSTAL GROWTH & DESIGN, 2014, 14 (07) :3576-3586

[4] Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites [J].

Bloch, Eric D. ;

Murray, Leslie J. ;

Queen, Wendy L. ;

Chavan, Sachin ;

Maximoff, Sergey N. ;

Bigi, Julian P. ;

Krishna, Rajamani ;

Peterson, Vanessa K. ;

Grandjean, Fernande ;

Long, Gary J. ;

Smit, Berend ;

Bordiga, Silvia ;

Brown, Craig M. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (37) :14814-14822

[5] Highly Selective Carbon Dioxide Uptake by [Cu(bpy-n)2(SiF6)] (bpy-1=4,4′-Bipyridine; bpy-2=1,2-Bis(4-pyridyl)ethene) [J].

Burd, Stephen D. ;

Ma, Shengqian ;

Perman, Jason A. ;

Sikora, Benjamin J. ;

Snurr, Randall Q. ;

Thallapally, Praveen K. ;

Tian, Jian ;

Wojtas, Lukasz ;

Zaworotko, Michael J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (08) :3663-3666

[6] Investigations on the Interaction of Dichloroaluminum Carboxylates with Lewis Bases and Water: an Efficient Road toward Oxo- and Hydroxoaluminum Carboxylate Complexes [J].

Bury, Wojciech ;

Chwojnowska, Elzbieta ;

Justyniak, Iwona ;

Lewinski, Janusz ;

Affek, Aneta ;

Zygadlo-Monikowska, Ewa ;

Bak, Joanna ;

Florjanczyk, Zbigniew .

INORGANIC CHEMISTRY, 2012, 51 (01) :737-745

[7] Metal-organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy [J].

Chaemchuen, Somboon ;

Kabir, Nawsad Alam ;

Zhou, Kui ;

Verpoort, Francis .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (24) :9304-9332

[8] Selective gas adsorption in a magnesium-based metal-organic framework [J].

Cheon, Young Eun ;

Park, Jungeun ;

Suh, Myunghyun Paik .

CHEMICAL COMMUNICATIONS, 2009, (36) :5436-5438

[9] An Amine-Functionalized MIL-53 Metal-Organic Framework with Large Separation Power for CO2 and CH4 [J].

Couck, Sarah ;

Denayer, Joeri F. M. ;

Baron, Gino V. ;

Remy, Tom ;

Gascon, Jorge ;

Kapteijn, Freek .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) :6326-+

[10] Structure, topology and property of metal-organic frameworks with pyridine-3,5-bis(phenyl-4-carboxylate) and varied metal centers [J].

Cui, Pei-Pei ;

Zhang, Xiu-Du ;

Zhao, Yue ;

Chen, Kai ;

Wang, Peng ;

Sun, Wei-Yin .

MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 208 :188-195

← 1 2 3 4 5 6 →