Bioactivity and corrosion properties of magnesium-substituted CaP coatings produced via electrochemical deposition

被引:33
作者
Bakin, B. [1 ]
Delice, T. Koc [1 ]
Tiric, U. [1 ]
Birlik, I. [2 ]
Azem, F. Ak [2 ]
机构
[1] Dokuz Eylul Univ, Grad Sch Nat & Appl Sci, Tinaztepe Campus, TR-35390 Izmir, Turkey
[2] Dokuz Eylul Univ, Fac Engn, Dept Met & Mat Engn, Tinaztepe Campus, TR-35390 Izmir, Turkey
关键词
CaP coatings; Bioactivity; Electrochemical deposition; Mg substitution; Ti alloys; Corrosion; CALCIUM-PHOSPHATE COATINGS; HYDROXYAPATITE; TITANIUM; ELECTRODEPOSITION; MORPHOLOGY; BEHAVIOR; STEEL; TIO2; SBF;
D O I
10.1016/j.surfcoat.2015.12.078
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Titanium (Ti) and its alloys are widely used as implant materials because of excellent mechanical properties and corrosion resistance. In order to improve the bone bonding ability, titanium is generally coated with osteoconductive biomaterials such as CaP ceramics. The aim of the study was to investigate the effect of Mg-substitution on corrosion and bioactivity properties of CaP coatings on Ti6AlV substrates produced electro-deposition technique. Chemical and morphological characterizations of the coatings were examined by using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). Corrosion properties of the coatings were studied electrochemically by potentiodynamic polarization technique in simulated body fluid (SBF) at 36 +/- 1 degrees C. Additionally, bioactivity properties of the coatings investigated in SBF with varying time 1, 7 and 14 days. In conclusion, Mg-substitution enhances the bioactivity properties but does not have an affirmative effect on corrosion properties of the coatings. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:29 / 35
页数:7
相关论文
共 24 条
[1]   Ultrastructural observation of single-crystal apatite fibres [J].
Aizawa, M ;
Porter, AE ;
Best, SM ;
Bonfield, W .
BIOMATERIALS, 2005, 26 (17) :3427-3433
[2]   Mg-substituted hydroxyapatite nanopowders: Synthesis, thermal stability and sintering behaviour [J].
Cacciotti, Ilaria ;
Bianco, Alessandra ;
Lombardi, Mariangela ;
Montanaro, Laura .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2009, 29 (14) :2969-2978
[3]   Improvement of bioactivity with magnesium and fluorine ions incorporated hydroxyapatite coatings via sol-gel deposition on Ti6Al4V alloys [J].
Cai, Yanli ;
Zhang, Sam ;
Zeng, Xianting ;
Wang, Yongsheng ;
Qjan, Min ;
Weng, Wenjian .
THIN SOLID FILMS, 2009, 517 (17) :5347-5351
[4]   Controlling the electrodeposition, morphology and structure of hydroxyapatite coating on 316L stainless steel [J].
Dinh Thi Mai Thanh ;
Pham Thi Nam ;
Nguyen Thu Phuong ;
Le Xuan Que ;
Nguyen Van Anh ;
Thai Hoang ;
Tran Dai Lam .
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2013, 33 (04) :2037-2045
[5]   In vitro corrosion behavior of electrodeposited calcium phosphate coatings on Ti6Al4V substrates [J].
Drevet, R. ;
Aaboubi, O. ;
Benhayoune, H. .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (09) :3069-3077
[6]   Bioactive coatings on Ti6Al4V alloy formed by plasma electrolytic oxidation [J].
Durdu, Salih ;
Usta, Metin ;
Berkem, Ali Sabri .
SURFACE & COATINGS TECHNOLOGY, 2016, 301 :85-93
[7]   Sonoelectrochemical deposition of calcium phosphates on carbon materials: effect of current density [J].
Han, H. M. ;
Phillips, G. J. ;
Mikhalovsky, S. V. ;
FitzGerald, S. ;
Lloyd, A. W. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2008, 19 (04) :1787-1791
[8]   Electrochemical Deposition and Characterization of Hydroxyapatite (HAp) on Titanium Substrate [J].
Isa, Nik Norziehana Che ;
Mohd, Yusairie ;
Yury, Norjanah .
2ND INTERNATIONAL CONFERENCE ON CHEMISTRY AND CHEMICAL PROCESS (ICCCP 2012), 2012, 3 :46-52
[9]   Electrodeposition of hydroxyapatite onto nanotubular TiO2 for implant applications [J].
Kar, A. ;
Raja, K. S. ;
Misra, M. .
SURFACE & COATINGS TECHNOLOGY, 2006, 201 (06) :3723-3731
[10]   In situ synthesis of magnesium-substituted biphasic calcium phosphate and in vitro biodegradation [J].
Kim, Tae-Wan ;
Lee, Hyeong-Shin ;
Kim, Dong-Hyun ;
Jin, Hyeong-Ho ;
Hwang, Kyu-Hong ;
Lee, Jong Kook ;
Park, Hong-Chae ;
Yoon, Seog-Young .
MATERIALS RESEARCH BULLETIN, 2012, 47 (09) :2506-2512