Flame-Retardant Effect of Sepiolite on an Intumescent Flame-Retardant Polypropylene System

被引:150
作者
Liu, Yun [1 ]
Zhao, Jing [1 ]
Deng, Cheng-Liang [1 ]
Chen, Li [1 ]
Wang, De-Yi [1 ]
Wang, Yu-Zhong [1 ]
机构
[1] Sichuan Univ, Ctr Degradable & Flame Retardant Polymer Mat ERCE, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Coll Chem,State Key Lab Polymer Mat Engn, Chengdu 610064, Peoples R China
基金
美国国家科学基金会;
关键词
THERMAL-DEGRADATION; CONE CALORIMETER; MONTMORILLONITE SYNERGISM; POLYETHYLENE; FLAMMABILITY; NANOCOMPOSITES; FORMULATIONS; MECHANISM; NITROGEN; BEHAVIOR;
D O I
10.1021/ie101737n
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Intumescent flame-retardant polypropylene-containing phosphorus and nitrogen compounds were enhanced significantly by adding a small amount of sepiolite as a synergistic agent The flame-retardant polypropylene composite was characterized by limiting oxygen index (LOI), UL-94, the cone calorimeter (CCT), and thermogravimetric analysis (TGA) to study the combustion behavior and thermal stability. The addition of 0.5% sepiolite increased the LOT from 29.8 to 31.8. The addition of sepiolite at a low additive amount appears to be an optimum blend ratio for the low heat release rate, total smoke, and CO2 production. Sepiolite also has a significant improvement in mechanical properties.
引用
收藏
页码:2047 / 2054
页数:8
相关论文
共 39 条
[21]   Synergistic effects of lanthanum oxide on a novel intumescent flame retardant polypropylene system [J].
Li, Yantao ;
Li, Bin ;
Dai, Jinfeng ;
Jia, He ;
Gao, Suliang .
POLYMER DEGRADATION AND STABILITY, 2008, 93 (01) :9-16
[22]   Flammability and thermal degradation of flame retarded polypropylene composites containing melamine phosphate and pentaerythritol derivatives [J].
Lv, P ;
Wang, ZZ ;
Hu, KL ;
Fan, WC .
POLYMER DEGRADATION AND STABILITY, 2005, 90 (03) :523-534
[23]   Intumescent flame retardant-montmorillonite synergism in ABS nanocomposites [J].
Ma, Haiyun ;
Tong, Lifang ;
Xu, Zhongbin ;
Fang, Zhengping .
APPLIED CLAY SCIENCE, 2008, 42 (1-2) :238-245
[24]   Preparation of polypropylene/sepiolite nanocomposites using supercritical CO2 assisted mixing [J].
Ma, J. ;
Bilotti, E. ;
Peijs, T. ;
Darr, J. A. .
EUROPEAN POLYMER JOURNAL, 2007, 43 (12) :4931-4939
[25]   Cone calorimeter analysis of UL-94 V-rated plastics [J].
Morgan, Alexander B. ;
Bundy, Matthew .
FIRE AND MATERIALS, 2007, 31 (04) :257-283
[26]   Development of fire-retarded materials - Interpretation of cone calorimeter data [J].
Schartel, B. ;
Hull, T. R. .
FIRE AND MATERIALS, 2007, 31 (05) :327-354
[27]  
Siat C, 1998, FIRE MATER, V22, P119, DOI 10.1002/(SICI)1099-1018(1998050)22:3<119::AID-FAM646>3.3.CO
[28]  
2-U
[29]   Synergistic effect of supported nickel catalyst with intumescent flame-retardants on flame retardancy and thermal stability of polypropylene [J].
Song, Rongjun ;
Zhang, Baoyan ;
Huang, Baotong ;
Tang, Tao .
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (06) :5988-5993
[30]   Polypropylene/montmorillonite nanocomposites and intumescent, flame-retardant montmorillonite synergism in polypropylene nanocomposites [J].
Tang, Y ;
Hu, Y ;
Li, BG ;
Liu, L ;
Wang, ZZ ;
Chen, ZY ;
Fan, WC .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (23) :6163-6173