Oxidative Carbonylations

被引：141

作者：

Gabriele, Bartolo ^{[1
]}

Salerno, Giuseppe ^{[2
]}

Costa, Mirco ^{[3
]}

机构：

[1] Univ Calabria, Dipartimento Sci Farmaceut, I-87036 Cosenza, Italy

[2] Univ Calabria, Dipartimento Chim, I-87036 Cosenza, Italy

[3] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

来源：

CATALYTIC CARBONYLATION REACTIONS | 2006年 / 18卷

关键词：

Carbon monoxide; Carbonyl compounds; Heterocycles; Homogeneous catalysis; Palladium iodide;

D O I：

10.1007/3418_024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The basic principles of the oxidative carbonylation reaction together with its synthetic applications are reviewed. In the first section, an overview of oxidative carbonylation is presented, and the general mechanisms followed by different substrates (alkenes, dienes, allenes, alkynes, ketones, ketenes, aromatic hydrocarbons, aliphatic hydrocarbons, alcohols, phenols, amines) leading to a variety of carbonyl compounds are discussed. The second section is focused on processes catalyzed by PdI2-based systems, and on their ability to promote different kind of oxidative carbonylations under mild conditions to afford important carbonyl derivatives with high selectivity and efficiency. In particular, the recent developments towards the one-step synthesis of new heterocyclic derivatives are described.

引用

页码：239 / 272

页数：34

共 311 条

[51] MECHANISTIC INVESTIGATION OF DECACARBONYLDIMANGANESE-CATALYZED CARBONYLATION OF AMINES [J].