[N,N′-bis-(6-methylpyrid-2-ylium)-(1R,2R)-1,2-diaminocyclohexane] bis-[(p-cymene)-trichlorouthenate(II)]

被引：11

作者：

Cabeza, JA ^{[1
]}

da Silva, I

del Río, I

García-Granda, S

机构：

[1] Univ Oviedo, CSIC, Inst Quim Organomet Enrique Moles, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain

[2] Univ Oviedo, Dept Quim Fis & Analit, E-33071 Oviedo, Spain

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 01期

关键词：

ruthenium; atropisomeric compounds; chiral compounds; crystal structure;

D O I：

10.1002/aoc.841

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The chiral compound (H(2)cydiampy)[RuCl3(p-cymene)](2) has been obtained in high yield by treating [RuCl2(p-cymene)](2) with an excess of hydrochloric acid in the presence of one equivalent of N,N'-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2-diaminocyclohexane (cydiampy). It crystallizes in the chiral tetragonal space group P4(3)2(1)2, with half of the atoms of the dication related to the other half by a crystallographic C-2 axis that also makes equivalent the two anionic metal moieties. Copyright (C) 2004 John Wiley Sons, Ltd.

引用

页码：209 / 210

页数：2

共 7 条

[1]

ANDREAS P, 2001, CHIMIA, V55, P708

[2] New chiral amino-phosphoramidite and bisphosphoramidite ligands derived from (R,R)-1,2-diaminocyclohexane:: application in Cu-catalyzed asymmetric conjugate addition of diethylzinc to 2-cyclohexenone [J].