The dimeric and two-dimensional copper(II) complexes constructed from salicylic acid and 4,4′-bipyridine

被引：28

作者：

Zhu, LG

Kitagawa, S

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[2] Kyoto Univ, Grad Sch Engn, Dept Synth Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

基金：

中国国家自然科学基金;

关键词：

crystal structure; copper complex; salicylic acid; 4,4 '-bipyridine; dimer; network;

D O I：

10.1016/S1387-7003(03)00173-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel complexes, [Cu-2(Hsal)(4)(4,4'-bipyridine)(H2O)(2)(DMF)(2)] (1) (H(2)sal = salicylic acid) and {[Cu(Hsal)(2)(4,4'-bipyridine)](H2O)(H(2)sal)}(n) (2), were synthesized by layered-solution method and structurally characterized. Geometries of copper atoms in both complexes exhibit square pyramidal. Complex 1 is a dimer and hydrogen bonds between water and DMF molecules extend the structure into ID hydrogen bonding network. Complex 2 consists of two-dimensional square framework structure. (C) 2003 Elsevier Science B.V. All rights reserved.

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收藏

页码：1051 / 1055

页数：5

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