DMF-exfoliated graphene for electrochemical NADH detection

被引：80

作者：

Keeley, Gareth P. ^{[1
,2
,3
]}

O'Neill, Arlene ^{[2
,4
]}

Holzinger, Michael ^{[1
]}

Cosnier, Serge ^{[1
]}

Coleman, Jonathan N. ^{[2
,4
]}

Duesberg, Georg S. ^{[2
,3
]}

机构：

[1] Univ Grenoble 1, ICMG FR 2607, UMR 5250, Dept Chim Mol,CNRS, F-38041 Grenoble 9, France

[2] Ctr Res Adapt Nanostruct & Nanodevices CRANN, Dublin 2, Ireland

[3] Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland

[4] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2011年 / 13卷 / 17期

关键词：

CARBON NANOTUBES; PYROLYTIC-GRAPHITE; DIAMOND ELECTRODES; GLASSY-CARBON; BIOSENSORS; FILMS;

D O I：

10.1039/c1cp20060g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical detection of NADH is of considerable interest because it is required as a cofactor in a large number of dehydrogenase-based biosensors. However, the presence of oxygenated functionalities on the electrode often causes fouling due to the adsorption of the oxidised form, NAD(+). Here we report an electroanalytical NADH sensor based on DMF-exfoliated graphene. The latter is shown to have a very low oxygen content, facilitating the exceptionally stable and sensitive detection of this important analyte.

引用

页码：7747 / 7750

页数：4

共 24 条

[1] Exploring the electrocatalytic sites of carbon nanotubes for NADH detection: an edge plane pyrolytic graphite electrode study [J].

Banks, CE ;

Compton, RG .

ANALYST, 2005, 130 (09) :1232-1239

[2] Graphene electrochemistry: an overview of potential applications [J].

Brownson, Dale A. C. ;

Banks, Craig E. .

ANALYST, 2010, 135 (11) :2768-2778

[3] Graphene-based materials in electrochemistry [J].

Chen, Da ;

Tang, Longhua ;

Li, Jinghong .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :3157-3180

[4] Electrochemistry at carbon nanotubes: perspective and issues [J].

Dumitrescu, Ioana ;

Unwin, Patrick R. ;

Macpherson, Julie V. .

CHEMICAL COMMUNICATIONS, 2009, (45) :6886-6901

[5] The Electrochemical Response of Graphene Sheets is Independent of the Number of Layers from a Single Graphene Sheet to Multilayer Stacked Graphene Platelets [J].

Goh, Madeline Shuhua ;

Pumera, Martin .

CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (11) :2355-2357

[6] High-yield production of graphene by liquid-phase exfoliation of graphite [J].

Hernandez, Yenny ;

Nicolosi, Valeria ;

Lotya, Mustafa ;

Blighe, Fiona M. ;

Sun, Zhenyu ;

De, Sukanta ;

McGovern, I. T. ;

Holland, Brendan ;

Byrne, Michele ;

Gun'ko, Yurii K. ;

Boland, John J. ;

Niraj, Peter ;

Duesberg, Georg ;

Krishnamurthy, Satheesh ;

Goodhue, Robbie ;

Hutchison, John ;

Scardaci, Vittorio ;

Ferrari, Andrea C. ;

Coleman, Jonathan N. .

NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568

[7] Electrochemical ascorbic acid sensor based on DMF-exfoliated graphene [J].

Keeley, Gareth P. ;

O'Neill, Arlene ;

McEvoy, Niall ;

Peltekis, Nikos ;

Coleman, Jonathan N. ;

Duesberg, Georg S. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (36) :7864-7869

[8]

Keeley GP, 2009, INT J ELECTROCHEM SC, V4, P794

[9] Electrochemical determination of nitrite at a bare glassy carbon electrode; why chemically modify electrodes? [J].

Kozub, Barbara R. ;

Rees, Neil V. ;

Compton, Richard G. .

SENSORS AND ACTUATORS B-CHEMICAL, 2010, 143 (02) :539-546

[10] Electroanalysis of NADH using conducting and redox active polymer/carbon nanotubes modified electrodes - A review [J].

Kumar, S. Ashok ;

Chen, Shen-Ming .

SENSORS, 2008, 8 (02) :739-766

← 1 2 3 →