Ultrathin Composite Polymeric Membranes for CO2/N2 Separation with Minimum Thickness and High CO2 Permeance

被引：39

作者：

Benito, Javier ^{[1
]}

Sanchez-Lainez, Javier ^{[2
]}

Zornoza, Beatriz ^{[2
]}

Martin, Santiago ^{[3
]}

Carta, Mariolino ^{[4
]}

Malpass-Evans, Richard ^{[4
]}

Tellez, Carlos ^{[2
]}

McKeown, Neil B. ^{[4
]}

Coronas, Joaquin ^{[2
]}

Gascon, Ignacio ^{[1
]}

机构：

[1] Univ Zaragoza, INA, Dept Quim Fis, C Pedro Cerbuna 12, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, INA, Dept Ingn Quim & Tecnol & Medio Ambiente, C Mariano Esquillor S-N, Zaragoza 50018, Spain

[3] Univ Zaragoza, ICMA, Dept Quim Fis, CSIC, C Pedro Cerbuna 12, E-50009 Zaragoza, Spain

[4] Univ Edinburgh, Sch Chem, David Brewster Rd, Edinburgh EH9 3FJ, Midlothian, Scotland

来源：

CHEMSUSCHEM | 2017年 / 10卷 / 20期

关键词：

combustion; gas separation; membranes; monolayers; polymers; INTRINSIC MICROPOROSITY; LANGMUIR-BLODGETT; GAS;

D O I：

10.1002/cssc.201701139

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of ultrathin films as selective layers in composite membranes offers significant advantages in gas separation for increasing productivity while reducing the membrane size and energy costs. In this contribution, composite membranes have been obtained by the successive deposition of approximately 1nm thick monolayers of a polymer of intrinsic microporosity (PIM) on top of dense membranes of the ultra-permeable poly[1-(trimethylsilyl)-1-propyne] (PTMSP). The ultrathin PIM films (30nm in thickness) demonstrate CO2 permeance up to seven times higher than dense PIM membranes using only 0.04% of the mass of PIM without a significant decrease in CO2/N-2 selectivity.

引用

页码：4014 / 4017

页数：4

共 50 条

[41] Separation of CO2/N2 on binderless 5A zeolite
Mendes, Patricia A. P.
Ribeiro, Ana M.
Gleichmann, Kristin
Ferreira, Alexandre F. P.
Rodrigues, Alirio E.
JOURNAL OF CO2 UTILIZATION, 2017, 20 : 224 - 233
[42] High flux acetate functionalized silica membranes based on in-situ co-condensation for CO2/N2 separation
Karimi, Somayeh
Korelskiy, Danil
Mortazavi, Yadollah
Khodadadi, Abbas Ali
Sardari, Kamyar
Esmaeili, Mohammad
Antzutkin, Oleg N.
Shah, Faiz Ullah
Hedlund, Jonas
JOURNAL OF MEMBRANE SCIENCE, 2016, 520 : 574 - 582
[43] Rapid synthesis of faujasite/polyethersulfone composite membrane and application for CO2/N2 separation
Wang, Bo
Sun, Chenhu
Li, Yanzuo
Zhao, Lin
Ho, W. S. Winston
Dutta, Prabir K.
MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 208 : 72 - 82
[44] A high CO2 permselective mesoporous silica/carbon composite membrane for CO2 separation
Li, Lin
Wang, Tonghua
Liu, Qingling
Cao, Yiming
Qiu, Jieshan
CARBON, 2012, 50 (14) : 5186 - 5195
[45] Membranes with a low loading of Metal-Organic Framework-Supported Ionic Liquids for CO2/N2 separation in CO2 capture
Monteiro, Bernardo
Nabais, Ana Rita
Almeida Paz, Filipe A.
Cabrita, Luis
Branco, Luis C.
Marrucho, Isabel M.
Neves, Luisa A.
Pereira, Claudia C. L.
ENERGY TECHNOLOGY, 2017, 5 (12) : 2158 - 2162
[46] Fabrication, characterisation and CO2/N2 gas permeance study of novel blended membrane
Farrukh, Sarah
Minhas, Fozia T.
Hussain, Arshad
Mujahid, Muhammad
INTERNATIONAL JOURNAL OF GLOBAL WARMING, 2015, 7 (04) : 532 - 547
[47] Computational evaluation of aluminophosphate zeotypes for CO2/N2 separation
Fischer, Michael
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (34) : 22801 - 22812
[48] A study on natural clinoptilolite for CO2/N2 gas separation
Karousos, Dionysios S.
Sapalidis, Andreas A.
Kouvelos, Evangelos P.
Romanos, George Em.
Kanellopoulos, Nickolaos K.
SEPARATION SCIENCE AND TECHNOLOGY, 2016, 51 (01) : 83 - 95
[49] Development of PAMAM dendrimer composite membranes for CO2 separation
Duan, Shuhong
Kouketsu, Takayuki
Kazama, Shingo
Yamada, Koichi
JOURNAL OF MEMBRANE SCIENCE, 2006, 283 (1-2) : 2 - 6
[50] Thickness Effect on Permeance of CO2/CH4 Gases in CA Coated PVDF Composite Membranes
Raza, Ayesha
Yousaf, Muhammad Fahad
Farrukh, Sarah
Hussain, Arshad
TRANSACTIONS OF THE INDIAN CERAMIC SOCIETY, 2021, 80 (02) : 89 - 95

← 1 2 3 4 5 →