Carbon dioxide capture in MOFs: The effect of ligand functionalization

被引：70

作者：

Kazemi, Sima ^{[1
]}

Safarifard, Vahid ^{[1
]}

机构：

[1] Iran Univ Sci & Technol, Dept Chem, Tehran 1684613114, Iran

来源：

POLYHEDRON | 2018年 / 154卷

关键词：

Metal-organic frameworks; Ligand design; Functionalization; CO2; capture; Functionalized composites; METAL-ORGANIC FRAMEWORK; GRAPHITE OXIDE COMPOSITES; SELECTIVE CO2 CAPTURE; ZEOLITIC IMIDAZOLATE FRAMEWORKS; ULTRASOUND-ASSISTED SYNTHESIS; GAS-ADSORPTION; AMIDE GROUPS; COORDINATION POLYMERS; ENHANCED HYDROGEN; POROUS MATERIALS;

D O I：

10.1016/j.poly.2018.07.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The carbon dioxide challenge is one of the most pressing problems facing our planet. Physisorption between certain adsorbents and CO2 molecules could allow conveniently reversible processes to capture CO2 gas. Metal-organic frameworks (MOFs) have recently attracted intense research interest because of their permanent porous structures, large surface areas, and potential applications as novel adsorbents. Tuning the interior pores of MOFs to improve their adsorption characteristics is considered an effective approach to enhance gas adsorption/separation performance. Recently, there is a growing interest to explore the impact of grafting functional groups with variable polarities (-NH2, -OH, -CO2H, -CF3, -SO3H, -NO2,(center dot center dot center dot)) onto the surfaces of MOFs through their organic ligands or directly coordinated to open metal centers on the CO2 capture/separation performance. Ligand functionalization in MOFs has been demonstrated to enhance gas adsorption and while ligand functionalization does not change the overall structure of the frameworks, it can influence the gas uptake behavior. In this review, we show how ligand functionalization influences the CO2 affinity and adsorption capacity of MOFs. The comparisons drawn in this review have sought to provide a roadmap for the future development of functionalized MOFs. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：236 / 251

页数：16

共 144 条

[11] Sorption kinetics of eight gases on a carbon molecular sieve at elevated pressure [J].

Bae, YS ;

Lee, CH .

CARBON, 2005, 43 (01) :95-107

[12] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[13] Isoreticular interpenetrated pillared-layer microporous metal-organic framework as a highly effective catalyst for three-component synthesis of pyrano [2, 3-d] pyrimidines [J].

Beheshti, Saeideh ;

Safarifard, Vahid ;

Morsali, Ali .

INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 94 :80-84

[14] Low concentration CO2 capture using physical adsorbents: Are metal-organic frameworks becoming the new benchmark materials? [J].

Belmabkhout, Youssef ;

Guillerm, Vincent ;

Eddaoudi, Mohamed .

CHEMICAL ENGINEERING JOURNAL, 2016, 296 :386-397

[15] Amides Do Not Always Work: Observation of Guest Binding in an Amide-Functionalized Porous Metal-Organic Framework [J].

Benson, Oguarabau ;

da Silva, Ivan ;

Argent, Stephen P. ;

Cabot, Rafel ;

Savage, Mathew ;

Godfrey, Harry G. W. ;

Yang, Yong ;

Parker, Stewart F. ;

Manuel, Pascal ;

Lennox, Matthew J. ;

Mitra, Tamoghna ;

Easun, Timothy L. ;

Lewis, William ;

Blake, Alexander J. ;

Besley, Elena ;

Yang, Sihai ;

Schroder, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (45) :14828-14831

[16] Tuning the target composition of amine-grafted CPO-27-Mg for capture of CO2 under post-combustion and air filtering conditions: a combined experimental and computational study [J].

Bernini, M. C. ;

Garcia Blanco, A. A. ;

Villarroel-Rocha, J. ;

Fairen-Jimenez, D. ;

Sapag, K. ;

Ramirez-Pastor, A. J. ;

Narda, G. E. .

DALTON TRANSACTIONS, 2015, 44 (43) :18970-18982

[17] Mixed-Component Sulfone Sulfoxide Tagged Zinc IRMOFs: In Situ Ligand Oxidation, Carbon Dioxide, and Water Sorption Studies [J].

Bryant, Macguire R. ;

Burrows, Andrew D. ;

Kepert, Cameron J. ;

Southon, Peter D. ;

Qazvini, Omid T. ;

Telfer, Shane G. ;

Richardson, Christopher .

CRYSTAL GROWTH & DESIGN, 2017, 17 (04) :2016-2023

[18] Facile synthesis and gas adsorption behavior of new functionalized Al-MIL-101-X (X = -CH3, -NO2, -OCH3, -C6H4, -F2, -(CH3)2, -(OCH3)2) materials [J].

Buragohain, Amlan ;

Van der Voort, Pascal ;

Biswas, Shyam .

MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 215 :91-97

[19] Highly Selective Carbon Dioxide Uptake by [Cu(bpy-n)2(SiF6)] (bpy-1=4,4′-Bipyridine; bpy-2=1,2-Bis(4-pyridyl)ethene) [J].

Burd, Stephen D. ;

Ma, Shengqian ;

Perman, Jason A. ;

Sikora, Benjamin J. ;

Snurr, Randall Q. ;

Thallapally, Praveen K. ;

Tian, Jian ;

Wojtas, Lukasz ;

Zaworotko, Michael J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (08) :3663-3666

[20] MOF-aminoclay composites for superior CO2 capture, separation and enhanced catalytic activity in chemical fixation of CO2 [J].

Chakraborty, Anindita ;

Achari, Amritroop ;

Eswaramoorthy, Muthusamy ;

Maji, Tapas Kumar .

CHEMICAL COMMUNICATIONS, 2016, 52 (76) :11378-11381

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