Metal-Organic Framework Nanoparticles

被引:486
作者
Wang, Shunzhi [1 ,2 ]
McGuirk, C. Michael [1 ,2 ,3 ]
d'Aquino, Andrea [1 ,2 ]
Mason, Jarad A. [1 ,2 ]
Mirkin, Chad A. [1 ,2 ]
机构
[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, 2145 Sheridan Rd, Evanston, IL 60208 USA
[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
metal-organic frameworks; modular nanomaterials; nanoparticle syntheses; surface functionalization; POROUS COORDINATION POLYMER; CHROMIUM TEREPHTHALATE MIL-101; PRUSSIAN BLUE NANOPARTICLES; DRUG-DELIVERY; MICROWAVE SYNTHESIS; CRYSTAL-GROWTH; THIN-FILMS; SURFACE; MOF; SIZE;
D O I
10.1002/adma.201800202
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Due to their well-defined 3D architectures, permanent porosity, and diverse chemical functionalities, metal-organic framework nanoparticles (MOF NPs) are an emerging class of modular nanomaterials. Herein, recent developments in the synthesis and postsynthetic surface functionalization of MOF NPs that strengthen the fundamental understanding of how such structures form and grow are highlighted; the internal structure and external surface properties of these novel nanomaterials are highlighted as well. These fundamental advances have resulted in MOF NPs being used as components in chemical sensors, biological probes, and membrane separation materials, as well as building blocks for colloidal crystal engineering.
引用
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页数:14
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