Gold-catalyzed addition of carbon nucleophiles to propargyl carboxylates

被引：103

作者：

Amijs, Catelijne H. M. ^{[1
]}

Opez-Carrillo, Veronica ^{[1
]}

Echavarren, Antonio M. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 20期

关键词：

D O I：

10.1021/ol701706d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Propargyl carboxylates react with 1,3-dicarbonyl compounds and electron-rich arenes in the presence of Au(l) catalysts to give enol carboxylates via alpha,beta-unsaturated Au(l) carbenes or Au(l)-coordinated allenes formed by 1,2- or 1,3-acyl migration, respectively.

引用

页码：4021 / 4024

页数：4

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