Transport properties of materials based on MF-4SC membranes and silica manufactured by a casting method

被引：14
|
作者：
Safronova, E. Yu. [1 ]
Yaroslavtsev, A. B. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 10期
关键词：
ION-TRANSPORT; FUEL-CELL; CONDUCTIVITY; ZIRCONIA; ACID;
D O I：
10.1134/S0036023610100013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Composites based on MF-4SC perfluorinated cation-exchange membranes were manufactured by casting from a polymer solution with a precursor for subsequent use in the synthesis of hydrous silica. Their proton conductivity was studied as a function of composition, temperature, and relative humidity. Modification of MF-4SC with small dopant amounts increases the water content and ion conductivity, in a reduced humidity, too. Materials containing 3% SiO2 by weight have a maximal conductivity.
引用
收藏
页码：1499 / 1502
页数：4
相关论文
共 50 条
  • [31] Multisensory systems with potentiometric sensors based on MF-4SC membranes for analysis of reconstituted milk
    A. V. Parshina
    E. A. Ryzhkova
    K. Yu. Yankina
    O. V. Bobreshova
    Petroleum Chemistry, 2016, 56 : 1042 - 1047
  • [32] Diffusion properties of bilayer membranes based on MC-40 and MF-4SC modified with silicon and zirconium oxides
    Yu. A. Karavanova
    Z. M. Kas’kova
    A. G. Veresov
    A. B. Yaroslavtsev
    Russian Journal of Inorganic Chemistry, 2010, 55 : 479 - 483
  • [33] Diffusion properties of bilayer membranes based on MC-40 and MF-4SC modified with silicon and zirconium oxides
    Karavanova, Yu A.
    Kas'kova, Z. M.
    Veresov, A. G.
    Yaroslavtsev, A. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (04) : 479 - 483
  • [34] Sorption and conducting properties of perfluorinated MF-4SC membranes in aqueous solutions containing phenylammonium ions
    A. A. -R. Sycheva
    I. V. Falina
    N. P. Berezina
    Russian Journal of Electrochemistry, 2009, 45 : 108 - 115
  • [35] Sorption and conducting properties of perfluorinated MF-4SC membranes in aqueous solutions containing phenylammonium ions
    Sycheva, A. A. -R.
    Falina, I. V.
    Berezina, N. P.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2009, 45 (01) : 108 - 115
  • [36] Diffusive Permeability of Hybrid Cation-Exchange Membranes MF-4SC/Halloysite Nanotubes
    Filippov, Anatoly
    Khanukaeva, Daria
    Afonin, Denis
    Skorikova, Galina
    Ivanov, Evgeny
    Vinokurov, Vladimir
    Lvov, Yuri
    2015 IEEE 15TH INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY (IEEE-NANO), 2015, : 208 - 211
  • [37] Theoretical and experimental investigation of interdiffusion in MF-4SC sulfonated cation-exchange membranes
    A. N. Filippov
    E. Yu. Safronova
    A. B. Yaroslavtsev
    Petroleum Chemistry, 2015, 55 : 406 - 410
  • [38] Theoretical and experimental investigation of interdiffusion in MF-4SC sulfonated cation-exchange membranes
    Filippov, A. N.
    Safronova, E. Yu.
    Yaroslavtsev, A. B.
    PETROLEUM CHEMISTRY, 2015, 55 (05) : 406 - 410
  • [39] Potentiometric Multisensory System Based on MF-4SC Membranes and Surface Modified Oxides for Analysis of Nicotinic Acid Pharmaceuticals
    A. V. Parshina
    G. Z. Habtemariam
    T. S. Kolganova
    E. Yu. Safronova
    O. V. Bobreshova
    Membranes and Membrane Technologies, 2021, 3 : 155 - 162
  • [40] Effect of modification of the MF-4SC membranes in the potassium form with acid salts of heteropolyacids on membrane properties and characteristics of dp sensors based on them
    E. Yu. Safronova
    A. V. Parshina
    E. A. Ryzhkova
    O. V. Bobreshova
    A. B. Yaroslavtsev
    Russian Journal of Inorganic Chemistry, 2016, 61 : 1512 - 1517
12345