Transport properties of materials based on MF-4SC membranes and silica manufactured by a casting method

被引：14

作者：

Safronova, E. Yu. ^{[1
]}

Yaroslavtsev, A. B. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 10期

关键词：

ION-TRANSPORT; FUEL-CELL; CONDUCTIVITY; ZIRCONIA; ACID;

D O I：

10.1134/S0036023610100013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Composites based on MF-4SC perfluorinated cation-exchange membranes were manufactured by casting from a polymer solution with a precursor for subsequent use in the synthesis of hydrous silica. Their proton conductivity was studied as a function of composition, temperature, and relative humidity. Modification of MF-4SC with small dopant amounts increases the water content and ion conductivity, in a reduced humidity, too. Materials containing 3% SiO2 by weight have a maximal conductivity.

引用

页码：1499 / 1502

页数：4

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