Large amplitude oscillatory extension of soft polymeric networks

被引:32
作者
Bejenariu, Anca Gabriela [1 ]
Rasmussen, Henrik Koblitz [2 ]
Skov, Anne Ladegaard [1 ]
Hassager, Ole [1 ]
Frankaer, Sarah Maria [1 ]
机构
[1] Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark
[2] Tech Univ Denmark, Dept Mech Engn, DK-2800 Lyngby, Denmark
关键词
Filament stretching rheometer; Large amplitude oscillation; Elastomer; Soft network; FILAMENT STRETCHING RHEOMETER; LINKED POLY(DIMETHYLSILOXANE) NETWORKS; UNIVERSAL TESTING PLATFORM; ENERGY DENSITY-FUNCTION; MULTIAXIAL DEFORMATIONS; MOLECULAR-WEIGHT; RUBBER ELASTICITY; VISCOSITY; MELTS; FLOW;
D O I
10.1007/s00397-010-0464-7
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
Using a filament stretching rheometer surrounded by a thermostatic chamber and equipped with a micrometric laser, it is possible to measure large amplitude oscillatory elongation (LAOE) on elastomeric based networks with no base flow as in the LAOE method for polymer melts. Poly(dimethylsiloxane)-based networks, considered as a model system for studying the development of soft elasticity, are mechanically characterised through reversed LAOE deformation, applying oscillatory measurements with several amplitudes and frequencies.
引用
收藏
页码:807 / 814
页数:8
相关论文
共 30 条
[1]   On controlling the kinematics of a filament stretching rheometer using a real-time active control mechanism [J].
Anna, SL ;
Rogers, C ;
McKinley, GH .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1999, 87 (2-3) :307-335
[2]   Elongational viscosity of narrow molar mass distribution polystyrene [J].
Bach, A ;
Almdal, K ;
Rasmussen, HK ;
Hassager, O .
MACROMOLECULES, 2003, 36 (14) :5174-5179
[3]   Extensional viscosity for polymer melts measured in the filament stretching rheometer [J].
Bach, A ;
Rasmussen, HK ;
Hassager, O .
JOURNAL OF RHEOLOGY, 2003, 47 (02) :429-441
[4]   CONNECTION BETWEEN POLYMER MOLECULAR-WEIGHT, DENSITY, CHAIN DIMENSIONS, AND MELT VISCOELASTIC PROPERTIES [J].
FETTERS, LJ ;
LOHSE, DJ ;
RICHTER, D ;
WITTEN, TA ;
ZIRKEL, A .
MACROMOLECULES, 1994, 27 (17) :4639-4647
[5]   Elongation-induced crystallization of a high molecular weight isotactic polybutene-1 melt compared to shear-induced crystallization [J].
Hadinata, Chitiur ;
Boos, Diana ;
Gabriel, Claus ;
Wassner, Erik ;
Ruellmann, Maximilian ;
Kao, Nhol ;
Laun, Martin .
JOURNAL OF RHEOLOGY, 2007, 51 (02) :195-215
[6]   Model networks based on 'endlinking' processes: Synthesis, structure and properties [J].
Hild, G .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (06) :1019-1149
[7]   Multiaxial deformations of end-linked poly (dimethylsiloxane) networks. III. Effect of entanglement density on strain-energy density function [J].
Kawamura, T ;
Urayama, K ;
Kohjiya, S .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2002, 40 (24) :2780-2790
[8]   Multiaxial deformations of end-linked poly(dimethylsiloxane) networks. 1. Phenomenological approach to strain energy density function [J].
Kawamura, T ;
Urayama, K ;
Kohjiya, S .
MACROMOLECULES, 2001, 34 (23) :8252-8260
[9]   Transient filament stretching rheometer .2. Numerical simulation [J].
Kolte, MI ;
Rasmussen, HK ;
Hassager, O .
RHEOLOGICA ACTA, 1997, 36 (03) :285-302
[10]   Elastic properties of nonstoichiometric reacted PDMS networks [J].
Larsen, AL ;
Hansen, K ;
Sommer-Larsen, P ;
Hassager, O ;
Bach, A ;
Ndoni, S ;
Jorgensen, M .
MACROMOLECULES, 2003, 36 (26) :10063-10070