Gold nanoclusters for ratiometric sensing of pH in extremely acidic media

被引:27
作者
Bonanno, Adele [1 ]
Perez-Herraez, Irene [2 ]
Zaballos-Garcia, Elena [1 ]
Perez-Prieto, Julia [2 ]
机构
[1] Univ Valencia, Dept Quim Organ, Ave Vicent Andres Estelles S-N, E-46100 Burjassot, Spain
[2] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain
关键词
INTRACELLULAR PH; NANOPARTICLES; NANOPROBES; RANGE; PROBE;
D O I
10.1039/c9cc08539d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
AuNCs capped with beta-nicotinamide adenine dinucleotide phosphate exhibit an outstanding performance as fluorescent pH sensors; specifically they exhibit a high emission in strongly acidic media and linear dependence on pH in extremely acidic media (0.6-2.7) as well as in the 7.0-9.2 pH range, while they are unresponsive at intermediate pH values. Remarkably, these AuNCs make ratiometric sensing possible in extremely acidic media with a single fluorophore, specifically the nanocluster itself.
引用
收藏
页码:587 / 590
页数:4
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