Promotion Effects of Platinum and Ruthenium on Carbon Nanotube Supported Cobalt Catalysts for Fischer-Tropsch Synthesis

被引：51

作者：

Zhang, Hui ^{[1
,2
]}

Chu, Wei ^{[2
]}

Zou, Changjun ^{[1
]}

Huang, Zhiyu ^{[1
]}

Ye, Zhongbin ^{[3
]}

Zhu, Lin ^{[1
]}

机构：

[1] SW Petr Univ, Dept Chem & Chem Engn, Chengdu 610500, Peoples R China

[2] Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China

[3] SW Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Explitat, Chengdu 610500, Peoples R China

来源：

CATALYSIS LETTERS | 2011年 / 141卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Carbon nanotube; Cobalt catalyst; Fischer-Tropsch synthesis; Platinum and ruthenium promoters; SILICA; ALUMINA; WATER; REDUCIBILITY; DISPERSION; CONVERSION; IRON; CO; SELECTIVITY; BEHAVIOR;

D O I：

10.1007/s10562-010-0536-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon nanotube supported nano-size monometallic and noble metal (Pt and Ru) promoted cobalt catalysts were prepared by incipient wetness impregnation (IWI) using solution of cobalt nitrate and characterized by nitrogen adsorption isotherm, X-ray diffraction (XRD), temperature programmed reduction, in situ magnetic method and TEM. Analysis of the magnetization and H-2-TPR data suggested promotion with platinum and ruthenium significantly decreased the cobalt species reduction temperature. TEM and XRD results showed that the presence of noble metal promoters had no significant effect on the size of cobalt for carbon naotube as catalytic support. Promotion of cobalt carbon nanotube-supported catalysts with small amounts of Pt and Ru resulted in slight increase in Fischer-Tropsch cobalt time yield. The Pt and Ru promoted cobalt catalyst exhibited carbon monoxide conversion of 37.1 and 31.4, respectively. C-5+ hydrocarbon selectivity was attained at 80.0%. The Pt promoted cobalt supported on carbon nanotube yielded better catalytic stability than that of the monometallic cobalt catalyst.

引用

页码：438 / 444

页数：7

共 43 条

[11] Glow-discharge plasma-assisted design of cobalt catalysts for Fischer-Tropsch synthesis [J].

Chu, Wei ;

Wang, Li-Nan ;

Chernavskii, Petr A. ;

Khodakov, Andrei Y. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (27) :5052-5055

[12] Cobalt species in promoted cobalt alumina-supported Fischer-Tropsch catalysts [J].

Chu, Wei ;

Chernavskii, Petr A. ;

Gengembre, Leon ;

Pankina, Galina A. ;

Fongarland, Pascal ;

Khodakov, Andrei Y. .

JOURNAL OF CATALYSIS, 2007, 252 (02) :215-230

[13] Fischer-Tropsch synthesis: A review of water effects on the performances of unsupported and supported Co catalysts [J].

Dalai, A. K. ;

Davis, B. H. .

APPLIED CATALYSIS A-GENERAL, 2008, 348 (01) :1-15

[14] Fischer-Tropsch synthesis: characterization and catalytic properties of rhenium promoted cobalt alumina catalysts [J].

Das, TK ;

Jacobs, G ;

Patterson, PM ;

Conner, WA ;

Li, JL ;

Davis, BH .

FUEL, 2003, 82 (07) :805-815

[15] Fischer-Tropsch reactions and the environment [J].

Dry, ME .

APPLIED CATALYSIS A-GENERAL, 1999, 189 (02) :185-190

[16] Cobalt dispersion, reducibility, and surface sites in promoted silica-supported Fischer-Tropsch catalysts [J].

Girardon, J.-S. ;

Quinet, E. ;

Griboval-Constant, A. ;

Chernavskii, P. A. ;

Gengembre, L. ;

Khodakov, A. Y. .

JOURNAL OF CATALYSIS, 2007, 248 (02) :143-157

[17] Optimization of the pretreatment procedure in the design of cobalt silica supported Fischer-Tropsch catalysts [J].

Girardon, JS ;

Constant-Griboval, A ;

Gengembre, L ;

Chernavskii, PA ;

Khodakov, AY .

CATALYSIS TODAY, 2005, 106 (1-4) :161-165

[18] Effect of cobalt precursor and pretreatment conditions on the structure and catalytic performance of cobalt silica-supported Fischer-Tropsch catalysts [J].

Girardon, JS ;

Lermontov, AS ;

Gengembre, L ;

Chernavskii, PA ;

Griboval-Constant, A ;

Khodakov, AY .

JOURNAL OF CATALYSIS, 2005, 230 (02) :339-352

[19] Preparation of novel titania supported palladium catalysts for selective hydrogenation of acetylene to ethylene [J].

Hong, Jingping ;

Chu, Wei ;

Chen, Muhua ;

Wang, Xiaodong ;

Zhang, Tao .

CATALYSIS COMMUNICATIONS, 2007, 8 (03) :593-597

[20] Evaluation of Ru-promoted Co/γ-Al2O3 catalysts in Fischer-Tropsch synthesis in a CSTR [J].

Hosseini, SA ;

Taeb, A ;

Feyzi, F .

CATALYSIS COMMUNICATIONS, 2005, 6 (03) :233-240

← 1 2 3 4 5 →