catena-poly[[manganese(II)-μ-[N,N,N′,N′-tetrakis(2-pyridylmethyl)hexane-1,6-diamine]] bis(perchlorate) acetone disolvate dihydrate]

被引：2
|
作者：
Hwang, In-Chul
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Ctr Funct Nano Fine Chem, Sch Appl Chem Engn, Kwangju 500757, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807038603
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Mn(C30H36N6)](ClO4)(2)center dot 2C(3)H(6)O center dot 2H(2)O, consists of a cationic complex polymer with counter-anions and solvent molecules. In the cationic polymer, Mn2+ ions are bridged by the hexadentate ligand N,N,N',N'-tetrakis(2-pyridylmethyl) hexane-1,6-diamine (tphn) to form a one-dimensional chain structure along the c axis. The repeat unit of the polymer, Mn-II(tphn), is disposed about a twofold axis passing through the Mn atom. The coordination geometry around the Mn centre is distorted octahedral.
引用
收藏
页码：M2302 / U510
页数：12
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