Selective electrochemical detection of hydrogen fluoride by ambiphilic ferrocene derivatives

被引：106

作者：

Bresner, C ^{[1
]}

Aldridge, S ^{[1
]}

Fallis, IA ^{[1
]}

Jones, C ^{[1
]}

Ooi, LL ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Ctr Fundamental & Appl Main Grp Chem, Cardiff CF10 3AT, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 23期

基金：

英国工程与自然科学研究理事会;

关键词：

molecular recognition; boron; electrochemistry; metallocenes; sensors;

D O I：

10.1002/anie.200500527

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Appropriate linking of Lewis acidic and Lewis basic components - in this case boronic acid and tertiary amine functionalities - allows the construction of a robust organometallic receptor capable of selectively binding hydrogen fluoride. This system can differentiate between exposure to HF and to related acids, such as HCl, by providing opposing electrochemical responses (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3606 / 3609

页数：4

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