Highly polar polymeric sorbents - Characterization and sorptive properties towards phenol and its derivatives

被引:70
作者
Trochimczuk, AW [1 ]
Streat, M
Kolarz, BN
机构
[1] Wroclaw Univ Technol, Inst Organ & Polymer Technol, PL-50370 Wroclaw, Poland
[2] Loughborough Univ Technol, Dept Chem Engn, Loughborough LE11 3TU, Leics, England
关键词
polar sorbents; phenol and its derivatives; sorption;
D O I
10.1016/S1381-5148(00)00056-0
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Six porous copolymers of acrylonitrile (AN)/divinylbenzene (DVB) and methacrylonitrile (MAN)/DVB have been synthesised by suspension polymerization in the presence of inert diluents. They have different specific surface area (460-720 m(2)/g for AN/DVB and 560-730 m(2)/g for MAN/DVR) and contain various amounts of the strongly polar nitrile groups, Their sorptive properties have been studied using dilute (0.5 mmol) solutions of phenol and its derivatives (o-chlorophenol, o-, m- and p-nitrophenol, 2,3- and 2,6-dimethylphenol, p-hydroxyphenol), It has been found that sorption of the most hydrophobic compounds and compounds capable of forming strong intramolecular hydrogen bonds does not depend on the polarity of the: polymer surface. Sorption of phenol and m- and p-nitrophenol is stronger on sorbents having more polar groups. The influence of these groups on the sorption process is highly significant in the case of hydrophilic, water soluble sorbates such as p-hydroxyphenol. Polymeric sorbents were characterized using elemental analysis, inverse gas chromatography and their porous structure was characterized by nitrogen adsorption at 77 K. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:259 / 271
页数:13
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