Isomerization-Induced Asymmetric Coordination Chemistry: From Auxiliary Control to Asymmetric Catalysis

被引：46
作者：
Gong, Lei [1 ]
Lin, Zhijie [1 ]
Harms, Klaus [1 ]
Meggers, Eric [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 43期
关键词：
asymmetric catalysis; auxiliary control; chirality; coordination chemistry; ruthenium; CHIRALITY;
D O I：
10.1002/anie.201003139
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Asymmetric generator: Chiral (S)-2-(isopropylsulfinyl)phenol and a more electron-rich methoxy derivative (R=OCH3) are capable of inducing and even catalyzing a chirality-generating trans-cis isomerization of two 2,2′-bipyridine ligands in an octahedral coordination sphere of a ruthenium complex. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：7955 / 7957
页数：3
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