Novel synthesis of electroresponsive poly(thiophenylene) through a Michael-type addition

被引:13
|
作者
Yamamoto, K [1 ]
Higuchi, M [1 ]
Takai, H [1 ]
Nishiumi, T [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan
关键词
D O I
10.1021/ol0068501
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel poly(thiophenylene) having N,N-diphenyl-1,4-phenylenediamine (PDA) as a redox unit was synthesized through a Michael-type addition. This polymerization proceeded at room temperature without catalysts. The polymer obtained acted as a good electroresponsive material with moderate thermostability.
引用
收藏
页码:131 / 134
页数:4
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