Electrochemical impedance spectroscopy investigation of chlorinated rubber-based coatings containing polyaniline as anticorrosion agent

被引：24

作者：

Baldissera, A. F. ^{[1
]}

Freitas, D. B. ^{[1
]}

Ferreira, C. A. ^{[1
]}

机构：

[1] Univ Fed Rio Grande do Sul, LAPOL PPGEM, BR-91501970 Porto Alegre, RS, Brazil

来源：

MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION | 2010年 / 61卷 / 09期

关键词：

CORROSION PROTECTION; MILD-STEEL; CONDUCTING POLYMERS; POLYPYRROLE COATINGS; BEHAVIOR; PERFORMANCE; MEMBRANES; IRON; PREVENTION; ELECTRODES;

D O I：

10.1002/maco.200905254

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Corrosion protection of mild steel by a newly developed chlorinated rubber (CR)-based coating system containing the inherently conductive polymer polyaniline (PAni) as an anticorrosion agent was studied. The synthesis of PAni and preparation of CR-based paint containing this polymer are described herein. The corrosion behavior of mild steel samples coated with a CR resin, CR/PAni-EB (emeraldine base), CR/PAni-ES (emeraldine salt), and CR/DBSA-doped PAni were investigated in 3.5% NaCl solution. For this purpose, electrochemical impedance spectroscopy and corrosion potential versus time measurements were utilized. It was found that the addition of the two forms of PAni, doped and undoped, to the CR resin increased its corrosion protection efficiency.

引用

页码：790 / 801

页数：12

共 56 条

[21] Effects of 160 MeV Ni12+ ion irradiation on polypyrrole conducting polymer electrode materials for all polymer redox supercapacitor [J].

Hussain, AMP ;

Saikia, D ;

Singh, F ;

Avasthi, DK ;

Kumar, A .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2005, 240 (04) :834-841

[22] On the use of conducting polymers to improve the resistance against corrosion of paints based on polyurethane resins [J].

Iribarren, J. I. ;

Armelin, E. ;

Liesa, F. ;

Casanovas, J. ;

Aleman, C. .

MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2006, 57 (09) :683-688

[23]

IRIBARREN JI, 2005, PROG ORG COAT, V52, P151

[24] Electrochemical characterization of polythiophene-coated steel [J].

Kousik, G ;

Pitchumani, S ;

Renganathan, NG .

PROGRESS IN ORGANIC COATINGS, 2001, 43 (04) :286-291

[25]

Lei LC, 2001, POLYM ADVAN TECHNOL, V12, P720, DOI 10.1002/pat.094

[26] Application of polypyrrole/TiO2 composite films as corrosion protection of mild steel [J].

Lenz, DM ;

Delamar, M ;

Ferreira, CA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 540 :35-44

[27]

Lupu S, 2002, ELECTROANAL, V14, P519, DOI 10.1002/1521-4109(200204)14:7/8<519::AID-ELAN519>3.0.CO

[28]

2-G

[29] Chemical reactivity of polypyrrole and its relevance to polypyrrole based electrochemical sensors [J].

Maksymiuk, Krzysztof .

ELECTROANALYSIS, 2006, 18 (16) :1537-1551

[30] Electrocatalytic dioxygen reduction at glassy carbon electrode modified with polyaniline grafted multiwall carbon nanotube film [J].

Manesh, Kalayd Manian ;

Santhosh, Padmanabhan ;

Gopalana, Anantha Lyengar ;

Lee, Kwang-Pill .

ELECTROANALYSIS, 2006, 18 (16) :1564-1571

← 1 2 3 4 5 6 →