Optical properties of Nd3+ and Er3+ ions in TeO2-WO3-PbO-La2O3 glasses

被引:28
作者
Burtan, Bozena [1 ]
Mazurak, Zbigniew [2 ]
Cisowski, Jan [1 ]
Czaja, Maria [3 ]
Lisiecki, Radoslaw [4 ]
Ryba-Romanowski, Witold [4 ]
Reben, Manuela [5 ]
Wasylak, Jan [5 ]
机构
[1] Cracow Univ Technol, Inst Phys, PL-30084 Krakow, Poland
[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland
[3] Silesian Univ, Fac Earth Sci, PL-41200 Sosnowiec, Poland
[4] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland
[5] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, PL-30059 Krakow, Poland
关键词
Luminescence properties; Nd3+-doped glasses; Er3+-doped glasses; Tellurite glasses; RARE-EARTH IONS; PHOSPHATE-GLASSES; TEMPERATURE; INTENSITIES; DECAY;
D O I
10.1016/j.optmat.2012.03.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Multicomponent telluride-tungstate glasses containing Nd3+ and Er3+ ions were studied experimentally at 77 and 293 K using spectroscopic methods. The Judd-Ofelt intensity parameters were derived from the absorption spectra and used to calculate the radiative lifetimes and branching ratios. The quantum efficiency eta = 0.95 of the F-4(3/2) level of Nd3+ ion is higher than the typical value of other tellurite-based glasses. For low concentration of Er3+ ions, the luminescence decay of the S-4(3/2) and I-4(11/2) levels is governed by radiative transitions and multiphonon relaxation involving the Te-O highest energy vibrations. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:2050 / 2054
页数:5
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