Phosphorus-Rich Ferrocenophanes

被引：9
作者：
Moser, Carmen [1 ,2 ]
Belaj, Ferdinand [1 ,2 ]
Pietschnig, Rudolf [1 ,2 ,3 ,4 ]
机构：
[1] Karl Franzens Univ Graz, Inst Chem, A-8010 Graz, Austria
[2] NaWi Graz, A-8010 Graz, Austria
[3] Univ Kassel, Inst Chem, D-34132 Kassel, Germany
[4] CINSaT, D-34132 Kassel, Germany
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2015年 / 190卷 / 5-6期
关键词：
crystal structure; aminophosphane; diphosphene; Ferrocenophane; tetraphosphetane; 1ST; DIPHOSPHENE; PPV;
D O I：
10.1080/10426507.2014.984025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Some novel phosphorus-rich [3]ferrocenophanes are reported with PPP or NPN bridge. The P-bridged ferrocenophanes are obtained from the corresponding diphosphenes by intramolecular thermal 2+2 addition. The reactivity of the diphosphenes toward hydrochlorination is explored as well. The NPN ferrocenophane is has been obtained via salt metathesis and is one of the rare examples of this compound class. Besides spectroscopic characterization, its structure was elucidated with X-ray crystallography.
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收藏
页码：837 / 844
页数：8
相关论文
共 14 条
  • [1] Organophosphorus π-conjugated materials
    Baumgartner, Thomas
    Reau, Regis
    [J]. CHEMICAL REVIEWS, 2006, 106 (11) : 4681 - 4727
  • [2] Chivers T, 2009, INORGANIC RINGS AND POLYMERS OF THE P-BLOCK ELEMENTS: FROM FUNDAMENTALS TO APPLICATIONS, pV
  • [3] Moser C, 2006, DALTON T, P3879, DOI 10.1039/b604501d
  • [4] Synthesis of 1,1′-ferrocenylene-bridged bisdiphosphenes
    Moser, Carmen
    Nieger, Martin
    Pietschnig, Rudolf
    [J]. ORGANOMETALLICS, 2006, 25 (10) : 2667 - 2672
  • [5] Syntheses, structures, and properties of the first stable 1,1′-bis(diphosphenyl)ferrocenes
    Nagahora, N
    Sasamori, T
    Tokitoh, N
    [J]. CHEMISTRY LETTERS, 2006, 35 (02) : 220 - 221
  • [6] A kinetically stabilized ferrocenyl diphosphene: Synthesis, structure, properties, and redox behavior
    Nagahora, N
    Sasamori, T
    Takeda, N
    Tokitoh, N
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (23) : 6146 - 6151
  • [7] Phosphaalkenylidene bridged ferrocenes
    Orthaber, Andreas
    Herber, Rolfe H.
    Pietschnig, Rudolf
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 719 : 36 - 40
  • [8] Synthesis, structure and π-delocalization of a phosphaalkenyl based neutral PNP-pincer
    Orthaber, Andreas
    Belaj, Ferdinand
    Pietschnig, Rudolf
    [J]. INORGANICA CHIMICA ACTA, 2011, 374 (01) : 211 - 215
  • [9] Synthesis, spectroscopic properties, and reactivity of ferrocenyl(2,4,6-tri-tert-butylphenyl)diphosphene
    Pietschnig, R
    Niecke, E
    [J]. ORGANOMETALLICS, 1996, 15 (02) : 891 - 893
  • [10] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
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