Facile synthesis of blue-emitting carbon dots@mesoporous silica composite spheres

被引:31
作者
Guo, Ziying [1 ]
Zhu, Zhenpeng [1 ]
Zhang, Xinguo [1 ]
Chen, Yibo [2 ]
机构
[1] Southern Med Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou 510515, Guangdong, Peoples R China
[2] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou Key Lab Environm Funct Mat & Technol, Guangzhou 510006, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon dot; Luminescence; Mesoporous silica; Composite material; HYDROTHERMAL TREATMENT; STEP SYNTHESIS; FLUORESCENCE; NANOPARTICLES; NITROGEN; GREEN;
D O I
10.1016/j.solidstatesciences.2017.12.011
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This paper reported a facile and effective approach towards high-efficient composite luminophores by embedding blue-emitting N-doped carbon dots into spherical SiO2 matrix (CDs@SiO2). Mesoporous silica microspheres (r-CDs@MSN) with strong luminescence were synthesized by removing CTAB templates in CDs@SiO2 using reflux with acetone. The r-CDs@MSN possess a spherical morphology with smooth surface and a diameter of 130 nm, while it exhibits an excitation-independent blue emission peak at 440 nm with an internal quantum yield of 21.5%. BET result shows that the corresponding surface area and adsorption total pore volume are 156.27 m(2)/g and 0.682 cm(3)/g, which is suitable for the drugs loading and release. The results indicate that r-CDs@MSN might act as a potential fluorescent drug carrier. (c) 2017 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:100 / 104
页数:5
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