Conductive poly (o-anisidine)/poly (ethylene terephthalate) nonwoven composite: Investigation of synthesis parameters and electromagnetic shielding effectiveness

被引:8
作者
Turay, Cevahir B. [1 ]
Erdogan, Meryem Kalkan [1 ]
Karakisla, Meral [1 ]
Sacak, Mehmet [1 ]
机构
[1] Ankara Univ, Dept Chem, TR-06100 Ankara, Turkey
关键词
Polyester; nonwoven; conductive composite; poly(o-anisidine); electromagnetic shielding effectiveness; CHEMICAL POLYMERIZATION; ELECTRICAL-PROPERTIES; POLYESTER FABRICS; POLYANILINE FILM; COATED FABRICS; POLYPYRROLE; FIBERS; HUMIDITY; BEHAVIOR; ANILINE;
D O I
10.1177/1528083715613629
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
A conductive poly(o-anisidine) (POA)/poly(ethylene terephthalate) (PET) nonwoven composite was prepared by chemical oxidative polymerization of o-anisidine in aqueous HCl solution. The effects of the oxidant type, oxidant/monomer mol ratio, and polymerization temperature and time were studied on POA content and surface resistivity of the composite. It was observed that the swelling of PET in 1,4-dioxane decreased the surface resistivity of the POA/PET composite by up to 18.5k/cm(2), when compared to that of the unswollen PET nonwoven. According to the electromagnetic shielding effectiveness (EMSE), and the relative shielding efficiency of the absorbance (A(b)) and reflectance (R-e) values of the composite in the range 15-1500MHz, 99.9% of the shielding was obtained with an attenuation of 33dB at 15MHz. The durability of the composite was determined by measuring its surface resistivity after domestic washing and commercial laundering.
引用
收藏
页码:1104 / 1120
页数:17
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