Manganese Complexes for (De)Hydrogenation Catalysis: A Comparison to Cobalt and Iron Catalysts

被引：469
作者：
Kallmeier, Fabian [1 ]
Kempe, Rhett [1 ]
机构：
[1] Univ Bayreuth, Inorgan Chem Catalyst Design 2, D-95440 Bayreuth, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 01期
关键词：
cobalt; dehydrogenation; hydrogenation; iron; manganese; ASYMMETRIC TRANSFER HYDROGENATION; PNP PINCER COMPLEXES; CARBON-DIOXIDE HYDROGENATION; NOBLE-METAL ACTIVITY; P-N-P'; PRIMARY ALCOHOLS; SELECTIVE HYDROGENATION; LEWIS-ACID; ENANTIOSELECTIVE HYDROGENATION; EFFICIENT HYDROGENATION;
D O I：
10.1002/anie.201709010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The sustainable use of the resources on our planet is essential. Noble metals are very rare and are diversely used in key technologies, such as catalysis. Manganese is the third most abundant transition metal of the Earth's crust and based on the recently discovered impressive reactivity in hydrogenation and dehydrogenation reactions, is a potentially useful noble-metal replacement. The hope of novel selectivity profiles, not possible with noble metals, is also an aim of such a replacement. The reactivity of manganese complexes in (de)hydrogenation reactions was demonstrated for the first time in 2016. Herein, we summarize the work that has been published since then and especially discuss the importance of homogeneous manganese catalysts in comparison to cobalt and iron catalysts.
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页码：46 / 60
页数：15
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