Polymeric composites;
Electrolyte;
Li plus -ion conductivity;
Functional;
D O I:
10.1016/j.matlet.2021.131623
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
A sandwich-like polyethylene oxide (PEO)-based polymer electrolyte membrane with a thickness of only 60 mu m is fabricated. The electrolyte is composed of a porous bacterial cellulose (BC) membrane, polymer matrix and lithium salt, fabricated by only one-step approach. The BC membrane provides strong mechanical property and physically prevents the lithium dendrite from unrestricted growth. Meanwhile, the presence of polar small molecule organics can not only increase the flexibility of polymer chain segments to enhance ion transport capacity, but also obtain a "soft contact" between the electrolyte-electrode. The BPP60% electrolyte shows enhanced electrochemical performance and LiFePO4/Li cell processes reliable charge-discharge cycle performance.
机构:
MOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions, Ministry of Education, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an,710072, ChinaMOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions, Ministry of Education, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an,710072, China
Huang, Ying
Li, Chao
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机构:
MOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions, Ministry of Education, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an,710072, ChinaMOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions, Ministry of Education, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an,710072, China
Li, Chao
Feng, Xuansheng
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h-index: 0
机构:
Shandong Provincial Key Laboratory of High Strength Lightweight Metallic Materials, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan,250014, ChinaMOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions, Ministry of Education, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an,710072, China