Fast-Charging Anode Materials and Novel Nanocomposite Design of Rice Husk-Derived SiO2 and Sn Nanoparticles Self-Assembled on TiO2(B) Nanorods for Lithium-Ion Storage Applications

被引:11
作者
Autthawong, Thanapat [1 ,2 ]
Yodbunork, Chawin [1 ,3 ]
Yodying, Waewwow [1 ]
Boonprachai, Ruttapol [1 ,2 ]
Namsar, Orapim [1 ]
Yu, Ai-Shui [4 ]
Chimupala, Yothin [2 ,5 ]
Sarakonsri, Thapanee [1 ,2 ,3 ]
机构
[1] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand
[2] Chiang Mai Univ, Fac Sci, Mat Sci Res Ctr, Chiang Mai 50200, Thailand
[3] Chiang Mai Univ, Fac Sci, Ctr Excellent Innovat Chem Perch CIC, Chiang Mai 50200, Thailand
[4] Fudan Univ, Dept Chem, Shanghai 200438, Peoples R China
[5] Chiang Mai Univ, Fac Sci, Dept Ind Chem, Chiang Mai 50200, Thailand
来源
ACS OMEGA | 2022年 / 7卷 / 01期
关键词
ELECTROCHEMICAL PERFORMANCE; COMPOSITES; BATTERIES; TIN; ELECTRODES; FACILE; SEI;
D O I
10.1021/acsomega.1c05982
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel microstructure of anode materials for lithium-ion batteries with ternary components, comprising tin (Sn), rice husk-derived silica (SiO2), and bronze-titanium dioxide (TiO2(B)), has been developed. The goal of this research is to utilize the nanocomposite design of rice husk-derived SiO2 and Sn nanoparticles self-assembled on TiO2(B) nanorods, Sn-SiO2@TiO2(B), through simple chemical route methods. Following that, the microstructure and electrochemical performance of as-prepared products were investigated. The major patterns of the X-ray diffraction technique can be precisely indexed as monoclinic TiO2(B). The patterns of SiO2 and Sn were found to be low in intensity since the particles were amorphous and in the nanoscale range, respectively. Small spherical particles, Sn and SiO2, attached to TiO2(B) nanorods were discovered. Therefore, the influence mechanism of Sn-SiO2@TiO2(B) fabrication was proposed. The Sn-SiO2@TiO2(B) anode material performed exceptionally well in terms of electrochemical and battery performance. The as-prepared electrode demonstrated outstanding stability over 500 cycles, with a high discharge capacity of similar to 150 mA h g(-1) at a fast-charging current of 5000 mA g(-1) and a low internal resistance of around 250.0 Omega. The synthesized Sn-SiO2@TiO2(B) nanocomposites have a distinct structure, the potential for fast charging, safety in use, and good stability, indicating their use as promising and effective anode materials in better power batteries for the next-generation applications.
引用
收藏
页码:1357 / 1367
页数:11
相关论文
共 65 条
[1]   Lithium Coordination Sites in LixTiO2(B): A Structural and Computational Study [J].
Armstrong, A. Robert ;
Arrouvel, Corinne ;
Gentili, Valentina ;
Parker, Stephen C. ;
Islam, M. Saiful ;
Bruce, Peter G. .
CHEMISTRY OF MATERIALS, 2010, 22 (23) :6426-6432
[2]   TiO2(B) nanotubes as negative electrodes for rechargeable lithium batteries [J].
Armstrong, G ;
Armstrong, AR ;
Canales, J ;
Bruce, PG .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (03) :A139-A143
[3]   Ultrafast-charging and long cycle-life anode materials of TiO2-bronze/nitrogen-doped graphene nanocomposites for high-performance lithium-ion batteries [J].
Autthawong, Thanapat ;
Chimupala, Yothin ;
Haruta, Mitsutaka ;
Kurata, Hiroki ;
Kiyomura, Tsutomu ;
Yu, Ai-shui ;
Chairuangsri, Torranin ;
Sarakonsri, Thapanee .
RSC ADVANCES, 2020, 10 (71) :43811-43824
[4]   Nanostructured diatom earth SiO2negative electrodes with superior electrochemical performance for lithium ion batteries [J].
Blanco, Maria Valeria ;
Renman, Viktor ;
Vullum-Bruer, Fride ;
Svensson, Ann Mari .
RSC ADVANCES, 2020, 10 (55) :33490-33498
[5]   Experimental studies on self-propagating high-temperature synthesis of Si-SiC composite from reactants of SiO2 derived from corn cob ash/C/Mg [J].
Chanadee, T. .
JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY, 2017, 53 (01) :245-252
[6]   Preparation and Characterization of ZnO Nanoparticles Supported on Amorphous SiO2 [J].
Chen, Ying ;
Ding, Hao ;
Sun, Sijia .
NANOMATERIALS, 2017, 7 (08)
[7]  
Chimupala Yothin, 2018, Solid State Phenomena, V283, P23, DOI 10.4028/www.scientific.net/SSP.283.23
[8]   Universal synthesis method for mixed phase TiO2(B)/anatase TiO2 thin films on substrates via a modified low pressure chemical vapour deposition (LPCVD) route [J].
Chimupala, Yothin ;
Junploy, Patcharanan ;
Hardcastle, Trevor ;
Westwood, Aidan ;
Scott, Andrew ;
Johnson, Benjamin ;
Brydson, Rik .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (15) :5685-5699
[9]   High surface area C/SiO2 composites from rice husks as a high-performance anode for lithium ion batteries [J].
Cui, Jinlong ;
Cheng, Fupeng ;
Lin, Jian ;
Yang, Jiachao ;
Jiang, Kuo ;
Wen, Zhongsheng ;
Sun, Juncai .
POWDER TECHNOLOGY, 2017, 311 :1-8
[10]   Anatase/TiO2-B hybrid microspheres constructed from ultrathin nanosheets: facile synthesis and application for fast lithium ion storage [J].
Cui, Peng ;
Xie, Bixia ;
Li, Xiaodan ;
Li, Meicheng ;
Li, Yaoyao ;
Wang, Yu ;
Liu, Zhuohai ;
Liu, Xin ;
Huang, Jing ;
Song, Dandan ;
Mbengue, Joseph Michel .
CRYSTENGCOMM, 2015, 17 (41) :7930-7937