Oxidation of 5-hydroxymethyl furfural to 2,5-diformylfuran in aqueous media over heterogeneous manganese based catalysts

被引：57
作者：
Neatu, F. [1 ]
Petrea, N. [2 ]
Petre, R. [2 ]
Somoghi, V. [3 ]
Florea, M. [1 ]
Parvulescu, V. I. [1 ]
机构：
[1] Univ Bucharest, Fac Chem, Dept Organ Chem Biochem & Catalysis, 4-12 Regina Elisabeta Bvd, Bucharest 030016, Romania
[2] CBRN Def & Ecol, Ctr Sci Res, 225 Oltenitei Sos, Bucharest 041309, Romania
[3] SC Stimpex SA, 46-48 Teclu Nicolae St, Bucharest 032368, Romania
来源：
CATALYSIS TODAY | 2016年 / 278卷
关键词：
Selective HMF oxidation to DFF; Heterogeneous catalysis; Manganese-copper layered double hydroxides; EFFICIENT AEROBIC OXIDATION; SELECTIVE OXIDATION; OXIDE CATALYSTS; AIR-QUALITY; BIOMASS; ACID; LDH; CONVERSION; RUTHENIUM; PHOSPHATE;
D O I：
10.1016/j.cattod.2016.03.031
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Manganese-copper layered double hydroxides prepared following a conventional procedure were investigated for the selective oxidation of 5-hydroxymethyl-2-furfural into 2,5-diformylfuran. After checking the effect of the different parameters it has been found that a composition corresponding to Mn-0.70 Cu0.05Al0.25, of the catalyst already calcined, led to the highest conversion (90%) and selectivity (87% in DFF). Noteworthy, this has been achieved working under mild aqueous conditions (90 degrees C and 8 bars O-2). The performances of the catalysts were closely associated to the strength of the basic sites. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：66 / 73
页数：8
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