Di-μ-chlorido-bis[dichloridobis(methylamido-κN)bis(methylamine-κN)-titanium(IV)]

被引：0

作者：

Thomas, Tegan ^{[1
]}

Pugh, David ^{[1
]}

Parkin, Ivan P. ^{[1
]}

Carmalt, Claire J. ^{[1
]}

机构：

[1] UCL, Dept Chem, London WC1H 0AJ, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2011年 / 67卷

基金：

英国工程与自然科学研究理事会;

关键词：

TITANIUM(IV); COMPLEXES;

D O I：

10.1107/S0108270111023353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Ti2Cl6(C2H6N)(2)(C2H7N)(2)], is a binuclear octahedral complex lying about an inversion centre. There are four different chloride environments, two terminal [Ti-Cl = 2.2847 (5) and 2.3371 (5) angstrom] and two bridging [Ti-Cl = 2.4414 (5) and 2.6759 (5) angstrom], with the Ti-Cl distances being strongly influenced by both the ligand trans to the chloride and whether or not the chloride anion is bridging between the two Ti-IV centres. The compound forms a two-dimensional network in the solid state, with weak intermolecular C-H center dot center dot center dot Cl interactions giving rise to a planar network in the (10 (2) over bar) plane.

引用

页码：M234 / M236

页数：3

共 22 条

[1] CIF applications. XV. enCIFer: a program for viewing, editing and visualizing CIFs [J].

Allen, FH ;

Johnson, O ;

Shields, GP ;

Smith, BR ;

Towler, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2004, 37 :335-338

[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[3] Synthesis and crystal structure of Cl3Ti[N(SiMe(2)Cl)(SiMe(2)NH(2))] [J].

Buheitel, R ;

Milius, W ;

Schnick, W .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (08) :1141-1144

[4]

Carmalt C.J., 2007, COMPREHENSIVE ORGANO, V12, P1

[5] THE SINGLE-SOURCE PRECURSOR CONCEPT - A CASE-STUDY OF GALLIUM-ARSENIDE [J].

COWLEY, AH ;

JONES, RA .

POLYHEDRON, 1994, 13 (08) :1149-1157

[6]

Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]

[7]

Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]

[8]

Jones A.C., 2009, Chemical Vapour Deposition: Precursors, Process and Applications

[9] Synthesis and structural characterisation of some highly hindered N-functionalised organoamido complexes of titanium(IV) and zirconium(IV) [J].

Jones, C ;

Junk, PC ;

Leary, SG ;

Smithies, NA .

INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (08) :1126-1128

[10]

Macrae CF, 2006, J APPL CRYSTALLOGR, V39, P453, DOI [10.1107/S002188980600731X, 10.1107/S0021 88980600731X]

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