Tetraarylphosphonium Salt-Catalyzed Carbon Dioxide Fixation at Atmospheric Pressure for the Synthesis of Cyclic Carbonates

被引：158

作者：

Toda, Yasunori ^{[1
]}

Komiyama, Yutaka ^{[1
]}

Kikuchi, Ayaka ^{[1
]}

Suga, Hiroyuki ^{[1
]}

机构：

[1] Shinshu Univ, Fac Engn, Dept Chem Mat, Wakasato, Nagano 3808553, Japan

来源：

ACS CATALYSIS | 2016年 / 6卷 / 10期

基金：

日本学术振兴会;

关键词：

chemical fixation; carbon dioxide; epoxides; cyclic carbonates; phosphonium salts; QUATERNARY PHOSPHONIUM SALT; CHEMICAL FIXATION; IONIC LIQUIDS; HYDROGEN-BOND; CO2; FIXATION; HOMOGENEOUS CATALYST; EFFICIENT CATALYSTS; ALUMINUM COMPLEXES; ORGANIC CARBONATES; ONIUM SALTS;

D O I：

10.1021/acscatal.6b02265

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phosphonium salts exhibit great utility in organic synthesis. However, tetraarylphosphonium salts (TAPS) have found limited use as catalysts. We demonstrate the TAPS-catalyzed carbon dioxide fixation at atmospheric pressure for the coupling reaction with epoxides. Five-membered cyclic carbonates were obtained, including enantio-enriched carbonates. Mechanistic studies revealed the origin of the behavior of TAPS to be the in situ formation of an active species by TAPS addition to epoxides via halohydrin intermediates.

引用

页码：6906 / 6910

页数：5

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