Synthesis and intermolecular interactions of N-benzylidenetyramines

被引：7

作者：

Maldonado, Mauricio ^{[1
]}

Perez-Redondo, Adrian ^{[2
]}

Quevedo, Rodolfo ^{[1
]}

机构：

[1] Univ Nacl Colombia, Fac Ciencias, Dept Quim, Carrera 30 45-03, Bogota, Colombia

[2] Univ Alcala de Henares, Dept Quim Organ & Quim Inorgan, E-28871 Alcala De Henares, Spain

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1127卷

关键词：

Tyramine; Schiff base; Hydrogen bond; Phenethylamine; Azomethine; MOLECULAR-STRUCTURE; SOLID-STATE; TYRAMINE;

D O I：

10.1016/j.molstruc.2016.08.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, the synthesis and intermolecular interactions between N-benzylidenetyramine molecules were investigated. The crystal structure of N-(4-nitrobenzylidene)tyramine shows a molecular organization in zigzag chains with intermolecular O-H center dot center dot center dot N hydrogen bonds between the azomethine and phenolic hydroxyl groups. Those chains are held together by C-H center dot center dot center dot O hydrogen bonds to generate layers, which are connected by C-H-O, pi center dot center dot center dot pi and NO2 center dot center dot center dot pi interactions. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：689 / 693

页数：5

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