Ruthenium-Catalyzed Conversion of Levulinic Acid to Pyrrolidines by Reductive Amination

被引：109

作者：

Huang, Yao-Bing ^{[1
]}

Dai, Jian-Jun ^{[1
]}

Deng, Xiao-Jian ^{[1
]}

Qu, Yan-Chao ^{[1
]}

Guo, Qing-Xiang ^{[1
]}

Fu, Yao ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Anhui Prov Key Lab Biomass Clean Energy, Hefei 230026, Peoples R China

来源：

CHEMSUSCHEM | 2011年 / 4卷 / 11期

基金：

中国国家自然科学基金;

关键词：

amination; amines; homogeneous catalysis; renewable resources; ruthenium;

D O I：

10.1002/cssc.201100344

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combo deal: An aqueous solution of levulinic acid (LA) and formic acid (FA) derived from biomass-based carbohydrates can be converted efficiently to pyrrolidines via a ruthenium catalyst without need for an energy-intensive separation of LA or an external H2 source. The ruthenium catalyst combines two processes: decomposition of FA to H2 and reductive amination of LA with an amine. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1578 / 1581

页数：4

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