Adsorptive removal of textile reactive dye using Posidonia oceanica (L.) fibrous biomass

被引：61
作者：
Ncibi, M. C. [1 ,2 ]
Mahjoub, B. [1 ,2 ]
Seffen, M. [2 ]
机构：
[1] High Inst Agron, Chem Lab, Chott Meriem 4042, Sousse, Tunisia
[2] EPAM Sousse, Appl Chem & Environm Res Unit, Chott Meriem 4000, Sousse, Tunisia
来源：
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY | 2007年 / 4卷 / 04期
关键词：
biosorption; posidonia seagrass; reactive dye; chemical treatments; modeling; AQUEOUS-SOLUTION; BIOSORPTION; SORPTION; EQUILIBRIUM; BIOSORBENT; CELLULOSE; WATER;
D O I：
10.1007/BF03325978
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The Mediterranean seagrass Posidonia oceanica (L) leaf sheaths were used as low cost, available and renewable biological adsorbent for the removal of reactive textile dye from aqueous solutions. Batch experiments were carried out for sorption kinetics and isotherms. Operating variables studied were temperature, pH and chemical pretreatment. Biosorption capacity seems to be enhanced by increasing the temperature. Maximum colour removal was observed at pH 5. Pre-treating fibres with H3PO4 and HNO3 solutions increased the adsorption efficiency up to 80%. Experimental sorption kinetic data were fitted to both Lagergren first-order and pseudo-second-order models and the data were found to follow first-order equation for raw fibres and pseudo-second-order for pre-treated ones. Equilibrium data were well represented by the Freundlich isotherm model for all tested adsorption systems. Besides, the thermodynamic study has showed that the dye adsorption phenomenon onto P. oceanica biomass was favourable, endothermic and spontaneous.
引用
收藏
页码：433 / 440
页数：8
相关论文
共 29 条
[1]   Removal of lead from aqueous solution using low cost abundantly available adsorbents [J].
Abdel-Ghani, N. T. ;
Hefny, M. ;
El-Chagbaby, G. A. F. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2007, 4 (01) :67-73
[2]   Application of biosorption for the removal of organic pollutants: A review [J].
Aksu, Z .
PROCESS BIOCHEMISTRY, 2005, 40 (3-4) :997-1026
[3]   A comparative study on the biosorption characteristics of some yeasts for Remazol Blue reactive dye [J].
Aksu, Z ;
Dönmez, G .
CHEMOSPHERE, 2003, 50 (08) :1075-1083
[4]   Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modelling [J].
Aksu, Z .
BIOCHEMICAL ENGINEERING JOURNAL, 2001, 7 (01) :79-84
[5]   Use of cellulose-based wastes for adsorption of dyes from aqueous solutions [J].
Annadurai, G ;
Juang, RS ;
Lee, DJ .
JOURNAL OF HAZARDOUS MATERIALS, 2002, 92 (03) :263-274
[6]   Removal of Cr from synthetic wastewater by sorption into volcanic ash soil [J].
Babel, S. ;
Opiso, E. M. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2007, 4 (01) :99-107
[7]   Adsorption characteristics of the dye, Brilliant Green, on Neem leaf powder [J].
Bhattacharyya, KG ;
Sarma, A .
DYES AND PIGMENTS, 2003, 57 (03) :211-222
[8]   Biosorption of textile dyes by biomass derived from Kluyveromyces marxianus IMB3 [J].
M. Bustard ;
G. McMullan ;
A. P. McHale .
Bioprocess Engineering, 1998, 19 (6) :427-430
[9]   Adsorption study for the removal of a basic dye: experimental and modeling [J].
Chakraborty, S ;
De, S ;
DasGupta, S ;
Basu, JK .
CHEMOSPHERE, 2005, 58 (08) :1079-1086
[10]   Removal of synthetic dyes from wastewaters:: a review [J].
Forgacs, E ;
Cserháti, T ;
Oros, G .
ENVIRONMENT INTERNATIONAL, 2004, 30 (07) :953-971
123