Coupling of Zinc Porphyrin Dyes and Copper Electrolytes: A Springboard for Novel Sustainable Dye-Sensitized Solar Cells

被引：32

作者：

Colombo, Alessia ^{[1
,2
,3
]}

Di Carlo, Gabriele ^{[1
,2
]}

Dragonetti, Claudia ^{[1
,2
,3
]}

Magni, Mirko ^{[1
,2
]}

Biroli, Alessio Orbelli ^{[2
,3
]}

Pizzotti, Maddalena ^{[1
,2
,3
]}

Roberto, Dominique ^{[1
,2
,3
]}

Tessore, Francesca ^{[1
,2
,3
]}

Benazzi, Elisabetta ^{[4
]}

Bignozzi, Carlo Alberto ^{[4
]}

Casarin, Laura ^{[4
]}

Caramori, Stefano ^{[4
]}

机构：

[1] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy

[2] UdR INSTM Milano, Via Golgi 19, I-20133 Milan, Italy

[3] CNR, ISTM, SmartMatLab Ctr, Via Golgi 19, I-20133 Milan, Italy

[4] Univ Ferrara, Dipartimento Sci Chim & Farmaceut, Via F Mortara, I-44121 Ferrara, Italy

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 22期

关键词：

COMPLEX REDOX SHUTTLES; PUSH-PULL; MEDIATORS; TIO2; EFFICIENCY; DSSCS; MESO; PHENANTHROLINES; GENERATION; DESIGN;

D O I：

10.1021/acs.inorgchem.7b02323

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of beta-substituted Zn2+ porphyrin dyes and copper-based electrolytes represents a sustainable route for economic and environmentally friendly dye-sensitized solar cells. Remarkably, a new copper electrolyte, [Cu(2-mesityl-1,10-phenanthroline)2] (+/2+), exceeds the performance reached by Co2+/3+ and I-/reference electrolytes.

引用

页码：14189 / 14197

页数：9

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