Coupling of Zinc Porphyrin Dyes and Copper Electrolytes: A Springboard for Novel Sustainable Dye-Sensitized Solar Cells

被引：32
作者：
Colombo, Alessia [1 ,2 ,3 ]
Di Carlo, Gabriele [1 ,2 ]
Dragonetti, Claudia [1 ,2 ,3 ]
Magni, Mirko [1 ,2 ]
Biroli, Alessio Orbelli [2 ,3 ]
Pizzotti, Maddalena [1 ,2 ,3 ]
Roberto, Dominique [1 ,2 ,3 ]
Tessore, Francesca [1 ,2 ,3 ]
Benazzi, Elisabetta [4 ]
Bignozzi, Carlo Alberto [4 ]
Casarin, Laura [4 ]
Caramori, Stefano [4 ]
机构：
[1] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy
[2] UdR INSTM Milano, Via Golgi 19, I-20133 Milan, Italy
[3] CNR, ISTM, SmartMatLab Ctr, Via Golgi 19, I-20133 Milan, Italy
[4] Univ Ferrara, Dipartimento Sci Chim & Farmaceut, Via F Mortara, I-44121 Ferrara, Italy
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 22期
关键词：
COMPLEX REDOX SHUTTLES; PUSH-PULL; MEDIATORS; TIO2; EFFICIENCY; DSSCS; MESO; PHENANTHROLINES; GENERATION; DESIGN;
D O I：
10.1021/acs.inorgchem.7b02323
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The combination of beta-substituted Zn2+ porphyrin dyes and copper-based electrolytes represents a sustainable route for economic and environmentally friendly dye-sensitized solar cells. Remarkably, a new copper electrolyte, [Cu(2-mesityl-1,10-phenanthroline)2] (+/2+), exceeds the performance reached by Co2+/3+ and I-/reference electrolytes.
引用
收藏
页码：14189 / 14197
页数：9
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