In situ carbon-supported titanium dioxide (ICS-TiO2) as an electrode material for high performance supercapacitors

被引:63
作者
Kumar, Rahul [1 ,2 ]
Singh, Balwant Kumar [1 ]
Soam, Ankur [3 ]
Parida, Smrutiranjan [1 ]
Sahajwalla, Veena [2 ]
Bhargava, Parag [1 ]
机构
[1] Indian Inst Technol, Dept Met Engn & Mat Sci, Mumbai 400076, Maharashtra, India
[2] Univ New South Wales, Sch Mat Sci & Engn, Ctr Sustainable Mat Res & Technol SMaRT, Sydney, NSW 2052, Australia
[3] Siksha O Anusandhan Univ, Dept Mech Engn, Khandagiri Sq, Bhubaneswar 751030, Odisha, India
来源
NANOSCALE ADVANCES | 2020年 / 2卷 / 06期
关键词
COUNTER ELECTRODE; COMPOSITE ELECTRODES; ENERGY-STORAGE; ELECTROCHEMICAL CAPACITANCE; PHOTOCATALYTIC ACTIVITY; TIO2; NANOPARTICLES; MESOPOROUS CARBON; OXIDE; GRAPHENE; NANOTUBES;
D O I
10.1039/d0na00014k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supercapacitors have attracted significant attention in the last few years as they have the capability to fulfill the demand for both power and energy density in many energy storage applications. In this study, anin situcarbon-supported titanium oxide (ICS-TiO2) electrode has been prepared using sucrose and TiO(2)powder. The ICS-TiO(2)powder was prepared by slipcasting, followed by the annealing of the TiO(2)slurry. Sucrose was added to the TiO(2)slurry as a soluble carbon source, and was converted into carbon at 600 degrees C then coated on the TiO(2)particles. The morphological and structural evolution of the electrode was investigated by FEG-SEM, FEG-TEM, XRD, BET, FTIR, XPS and Raman spectroscopy. The electrochemical characterization of ICS-TiO(2)demonstrated that this material exhibits an efficient value of specific capacitance (277.72 F g(-1)at 25 mV s(-1)) for charge storage. ISC-TiO(2)also exhibits a specific capacitance of 180 F g(-1)at 2 A g(-1)in a 1 M Na(2)SO(4)aqueous electrolyte. The results suggest that ICS-TiO(2)can be utilized as a high-performance electrode material for supercapacitors with desirable electrochemical properties.
引用
收藏
页码:2376 / 2386
页数:11
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