Dehydrogenative borylation: the dark horse in metal-catalyzed hydroborations and diborations?

被引：28

作者：

Geier, Stephen J. ^{[1
]}

Westcott, Stephen A. ^{[1
]}

机构：

[1] Mt Allison Univ, Dept Chem & Biochem, Sackville, NB E4L 1G8, Canada

来源：

REVIEWS IN INORGANIC CHEMISTRY | 2015年 / 35卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

boron; borylation; catalysis; hydroboration; transition metals; PROMOTED REACTIONS; BORON HYDRIDES; B-H; STEREOSELECTIVE-SYNTHESIS; RHODIUM COMPLEXES; TERMINAL ALKYNES; SYNTHETIC ROUTE; ALKENES; IRIDIUM; LIGAND;

D O I：

10.1515/revic-2014-0008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-catalyzed hydroborations and diborations frequently give "unwanted" side products arising from a competing dehydrogenative borylation reaction. While catalyst development initially focused on avoiding this "deleterious" pathway, fine tuning of a catalyst system could provide an efficient method to generate unsaturated alkenylboronate esters, synthetically valuable synthons for the Suzuki-Miyaura cross-coupling reaction. The aim of this review is to highlight the history and development of the dehydrogenative borylation reaction in the metal-catalyzed synthesis of alkenylboronate esters.

引用

页码：69 / 79

页数：11

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