Selective monofunctionalization of tri-urea-mono-acetamides of calix[4]arenes on the narrow rim

被引：3

作者：

Rudzevich, Yuliya ^{[1
]}

Rudzevich, Valentyn ^{[1
]}

Bolte, Michael ^{[2
,3
]}

Boehmer, Volker ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Abt Lehramt Chem, Fachbereich Chem Pharm & Geowissensch, D-55099 Mainz, Germany

[2] Univ Frankfurt, Fachbereich Chem, Inst Anorgan Chem, D-60438 Mainz, Germany

[3] Univ Frankfurt, Pharm Wissensch, Inst Anorgan Chem, D-60438 Mainz, Germany

来源：

SYNTHESIS-STUTTGART | 2008年 / 05期

关键词：

calixarenes; alkylations; carboxylic acids; self-assembly; supramolecular chemistry;

D O I：

10.1055/s-2008-1032155

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of calix[4]arenes substituted at their wide rim by three 3-aryl-urea and one acetamide group and at their narrow rim by three alkyl ether groups and one ether group ending in a carboxy function is described. The reaction sequence ensures that these functional groups are attached to the same phenolic unit. Two key intermediates have been additionally characterized by X-ray crystal structure analysis.

引用

页码：754 / 762

页数：9

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