Selective monofunctionalization of tri-urea-mono-acetamides of calix[4]arenes on the narrow rim

被引：3
|
作者：
Rudzevich, Yuliya [1 ]
Rudzevich, Valentyn [1 ]
Bolte, Michael [2 ,3 ]
Boehmer, Volker [1 ]
机构：
[1] Johannes Gutenberg Univ Mainz, Abt Lehramt Chem, Fachbereich Chem Pharm & Geowissensch, D-55099 Mainz, Germany
[2] Univ Frankfurt, Fachbereich Chem, Inst Anorgan Chem, D-60438 Mainz, Germany
[3] Univ Frankfurt, Pharm Wissensch, Inst Anorgan Chem, D-60438 Mainz, Germany
来源：
SYNTHESIS-STUTTGART | 2008年 / 05期
关键词：
calixarenes; alkylations; carboxylic acids; self-assembly; supramolecular chemistry;
D O I：
10.1055/s-2008-1032155
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of calix[4]arenes substituted at their wide rim by three 3-aryl-urea and one acetamide group and at their narrow rim by three alkyl ether groups and one ether group ending in a carboxy function is described. The reaction sequence ensures that these functional groups are attached to the same phenolic unit. Two key intermediates have been additionally characterized by X-ray crystal structure analysis.
引用
收藏
页码：754 / 762
页数：9
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