Sonoluminescence of aqueous solutions of sulfuric acid and sulfur dioxide

被引:14
|
作者
Sharipov, GL
Abdrakhmanov, AM
Gainetdinov, RK
机构
[1] Bashkortostan Republ Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia
[2] Russian Acad Sci, Ufa Res Ctr, Ufa 450075, Russia
关键词
sonoluminescence; aqueous solutions; sulfuric acid; sulfur dioxide;
D O I
10.1023/B:RUCB.0000009639.39650.14
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sonoluminescence (SL) of aqueous solutions of sulfuric acid and sulfur dioxide enhances with an increase in their concentration and reaches a maximum at 16 and 0.05 mol L-1, respectively. The further increase in the concentration of these substances decreases the SL intensity. The SL spectra of the solutions have a broad maximum at 450 nm. Excited SO2 molecules formed in sulfuric acid due to sonolysis are luminescence emitters. The proposed mechanism of bright SL in these systems is based on the energy transfer from the electron-excited sonolysis products to the SO2 molecules in cavitation bubbles.
引用
收藏
页码:1966 / 1968
页数:3
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