Preparation, Crystal Structure and Explosive Properties of Copper(II) Perchlorate Complex with 4-Amino-1,2,4-Triazole and Water

被引：22

作者：

Cudzilo, Stanislaw ^{[1
]}

Trzcinski, Waldemar ^{[1
]}

Nita, Marcin ^{[1
]}

Michalik, Slawomir ^{[2
]}

Krompiec, Stanislaw ^{[2
]}

Kruszynski, Rafal ^{[3
]}

Kusz, Joachim ^{[4
]}

机构：

[1] Mil Tech Acad, Inst Chem, PL-00908 Warsaw, Poland

[2] Silesian Univ, Inst Chem, PL-40006 Katowice, Poland

[3] Tech Univ Lodz, PL-90924 Lodz, Poland

[4] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2011年 / 36卷 / 02期

关键词：

4-Amino-1,2,4-Triazole; Complex Copper Perchlorate; Explosive Properties; X-Ray Structure; COORDINATION POLYMERS;

D O I：

10.1002/prep.201000054

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A complex from copper(II) perchlorate with 4-amino-1,2,4-triazole (4-AT, C2H4N4) was synthesized, and elemental composition, molecular structure, and explosive properties were determined. To this end, elemental and X-ray analyses were carried out, sensitivity to mechanical and thermal stimuli was measured, mechanism of thermal decomposition was investigated, and kinetic parameters of decomposition were determined. In the next step measurements of heat of combustion and detonation velocity were performed. Detonation parameters were also calculated. It was stated that the complex has slightly distorted square bipyramidal (4 + 2) coordination. The four basal bonds are formed by nitrogen atoms of four 4-AT molecules. The coordination of the metal is completed by two axial oxygen atoms, one of the perchlorate ion, and one of the water molecule. With respect to explosive properties, tetrakis(4-AT)copper(11) perchlorate monohydrate belongs to the group of sensitive secondary explosives.

引用

页码：151 / 159

页数：9

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