Diels-Alder Chemistry of Graphite and Graphene: Graphene as Diene and Dienophile

被引：223

作者：

Sarkar, Santanu

Bekyarova, Elena

Niyogi, Sandip

Haddon, Robert C. ^{[1
]}

机构：

[1] Univ Calif Riverside, Ctr Nanoscale Sci & Engn, Dept Chem, Riverside, CA 92521 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 10期

关键词：

WALL CARBON NANOTUBES; CHEMICAL-MODIFICATION; ADDUCTS; C-60; FUNCTIONALIZATION; FULLERENES; GAS;

D O I：

10.1021/ja200118b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strategy for the reversible modification of the electronic properties of graphene under very mild conditions.

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页码：3324 / 3327

页数：4

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