Crystal growth and optical properties of non-UV absorption K2Al2B2O7 crystals

被引:22
作者
Liu, Chunlei [1 ,2 ]
Liu, Lijuan [1 ]
Zhang, Xin [1 ,2 ]
Wang, Lirong [1 ,2 ]
Wang, Guiling [1 ]
Chen, Chuangtian [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
关键词
UV absorption; Nonlinear optical crystal;
D O I
10.1016/j.jcrysgro.2010.11.175
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In this paper, large and transparent K2Al2B2O7 (KABO) crystals were grown using NaF as a flux in a non-oxygen atmosphere for the first time. Through optimization of the growth condition, bulk KABO crystal has been obtained with good quality. The transmittance spectrum shows that the abnormal UV absorption from 200 to 300 nm of KABO crystals could be effectively eliminated by this new method. The non-UV absorption KABO crystal is promising for the application of fourth harmonic generation of Nd:YAG lasers. A 280 mW average output power was obtained through fourth harmonic generation of Nd:YAG laser with 10 kHz, 10 ns pulse and a 8.85-mm-thick KABO crystal. The conversion efficiency up to 33.4% of second harmonic generation from 532 to 266 nm has also been achieved with a 25 ps, 10 Hz laser system and the same crystal. To our knowledge, this is the highest result at present. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:618 / 620
页数:3
相关论文
共 8 条
[1]   K2Al2B2O7 -: A new nonlinear optical crystal [J].
Hu, ZG ;
Mori, Y ;
Higashiyama, T ;
Yoshimura, M ;
Yap, YK ;
Kagebayashi, Y ;
Sasaki, T .
ELECTRO-OPTIC AND SECOND HARMONIC GENERATION MATERIALS, DEVICES, AND APPLICATIONS II, 1998, 3556 :156-161
[2]   Flux growth of the new nonlinear optical crystal:: K2Al2B2O7 [J].
Hu, ZG ;
Higashiyama, T ;
Yoshimura, M ;
Mori, Y ;
Sasaki, T .
JOURNAL OF CRYSTAL GROWTH, 2000, 212 (1-2) :368-371
[3]   Effect of dislocations on the optical homogeneity and UV absorption of KABO crystals [J].
Liu, Lijuan ;
Chen, Chuangtian .
JOURNAL OF CRYSTAL GROWTH, 2006, 292 (02) :472-475
[4]   Impact of Fe3+ on UV absorption of K2Al2B2O7 crystals [J].
Liu, Lijuan ;
Liu, Chunlei ;
Wang, Xiaoyang ;
Hu, Z. G. ;
Li, R. K. ;
Chen, C. T. .
SOLID STATE SCIENCES, 2009, 11 (04) :841-844
[5]  
NISHIOKA M, 2003, P C LAS EL CTUF2
[6]   Two new nonlinear optical crystals:: BaAl2B2O7 and K2Al2B2O7 [J].
Ye, N ;
Zeng, WR ;
Wu, BC ;
Chen, CT .
ELECTRO-OPTIC AND SECOND HARMONIC GENERATION MATERIALS, DEVICES, AND APPLICATIONS II, 1998, 3556 :21-23
[7]   New nonlinear optical crystal K2Al2B2O7 [J].
Ye, N ;
Zeng, WR ;
Jiang, J ;
Wu, BC ;
Chen, CT ;
Feng, BH ;
Zhang, XL .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2000, 17 (05) :764-768
[8]   Growth of large K2Al2B2O7 crystals [J].
Zhang, CQ ;
Wang, JY ;
Hu, XB ;
Jiang, HD ;
Liu, YG ;
Chen, CT .
JOURNAL OF CRYSTAL GROWTH, 2002, 235 (1-4) :1-4